1440513-12-1

Basic information

• Product Name: C₁₄H₁₁ClHgN₂O
• CAS NO: 1440513-12-1
• Molecular Weight: 459.297
• Mol File: 1440513-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₁ClHgN₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₁ClHgN₂O(1440513-12-1)
• EPA Substance Registry System: C₁₄H₁₁ClHgN₂O(1440513-12-1)

Safety Data

• Hazardous Substances Data: 1440513-12-1(Hazardous Substances Data)

Upstream product

• 1440513-09-6 C₁₄H₁₄N₂O₂ 
• 4467-07-6 3-(pyridin-2-yl)benzoic acid 
• 4373-61-9 2-(m-tolyl)pyridine 
• 109-04-6 2-bromo-pyridine 
• 591-17-3 meta-bromotoluene 
• 1440513-11-0 1-(2-oxazolinyl)-3-(2-pyridyl)benzene 
• 1600-27-7 mercury(II) diacetate 

Relevant articles and documents

NCN palladium pincer via transmercuration. Synthesis of [2-(2-oxazoliny)-6-(2-pyridyl)] phenylpalladium(II) chloride and its catalytic activity in Suzuki coupling

The unsymmetrical NCN ligand 1-(2-oxazolinyl)-3-(2-pyridyl)benzene 6 was synthesized starting from m-bromotoluene after a series of transformations. The reaction of 6 and mercury (II) acetate resulted in mercurial derivative 7 which was transformed into the corresponding NCN palladium pincer 8 via transmercuration. The ultraviolet spectra of 6-8 in acetonitrile were also studied. The structures of 6 and 8 were further confirmed by X-ray single crystal diffraction. The carbon-carbon cross coupling reactions between aryl halides and phenylboronic acid catalyzed by 8 were investigated. The results indicate that this palladium pincer is more highly active to the coupling of aryl bromides than aryl chlorides.