1440569-85-6

Basic information

• Product Name: C₂₀H₂₄OSi
• Synonyms: C₂₀H₂₄OSi
• CAS NO: 1440569-85-6
• Molecular Weight: 308.495
• Mol File: 1440569-85-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₄OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₄OSi(1440569-85-6)
• EPA Substance Registry System: C₂₀H₂₄OSi(1440569-85-6)

Safety Data

• Hazardous Substances Data: 1440569-85-6(Hazardous Substances Data)

Upstream product

• 460095-28-7 4-(tert-butyldiphenylsilyl)but-3-yn-2-one 

Downstream Products

• 2914-69-4 (S)-(-)-3-butyn-2-ol 
• 42969-65-3 (R)-(+)-3-butyn-2-ol 

Relevant articles and documents

Asymmetric hydrogenation of alkynyl ketones with the η6- arene/TsDPEN-ruthenium(II) catalyst

Enantioselective hydrogenation of alkynyl ketones catalyzed by Ru(OTf)(TsDPEN)(η6-p-cymene) (TsDPEN = N-(p-toluenesulfonyl)-1,2- diphenylethylenediamine) affords the propargylic alcohols in up to 97% ee. The alkynyl moieties are left intact in most cases. The reaction can be conducted with a substrate-to-catalyst molar ratio as high as 5000 under 10 atm of H 2. The mode of enantioselection is elucidated with the transition state models directed by the CH/π attractive interaction between the substrate and the catalytic species.