144709-79-5

Basic information

• Product Name: Ethanone, 2-(1-cyclohexen-1-yl)-1-[2-(trimethylsilyl)-2-cyclohexen-1-yl]-
• CAS NO: 144709-79-5
• Molecular Formula: C17H28OSi
• Molecular Weight: 276.494
• Mol File: 144709-79-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(1-cyclohexen-1-yl)-1-[2-(trimethylsilyl)-2-cyclohexen-1-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(1-cyclohexen-1-yl)-1-[2-(trimethylsilyl)-2-cyclohexen-1-yl]-(144709-79-5)
• EPA Substance Registry System: Ethanone, 2-(1-cyclohexen-1-yl)-1-[2-(trimethylsilyl)-2-cyclohexen-1-yl]-(144709-79-5)

Safety Data

• Hazardous Substances Data: 144709-79-5(Hazardous Substances Data)

Upstream product

• 84189-13-9 cyclohexene-1-acetyl chloride 
• 17874-17-8 cyclohex-1-enyl-trimethyl-silane 

Relevant articles and documents

Formation of 2-cyclohexenones by Friedel-Crafts acylation of alkenes with β,γ-ethylenic acyl halides

Friedel-Crafts acylation of alkenes with β,γ-alkenoyl halides leads to conjugated Al-trienolates able to cyclize into Al-enolates of 2-cyclohexenones through an allowed thermal disrotary electrocyclization mechanism. Discussion of the product structures is based on two-dimensional NMR experiments (400 MHz) and molecular mechanics studies (GENMOL and MM2).