17874-17-8

Basic information

• Product Name: 1-Cyclohexenyltrimethylsilane
• Synonyms: (1-Cyclohexen-1-yl)trimethylsilane;1-(Trimethylsilyl)-1-cyclohexene;1-Cyclohexenyltrimethylsilane;1-Trimethylsilyl-1-cyclohexene;1-Trimethylsilylcyclohexan-1-ene
• CAS NO: 17874-17-8
• Molecular Formula: C₉H₁₈Si
• Molecular Weight: 154.32
• Mol File: 17874-17-8.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Cyclohexenyltrimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexenyltrimethylsilane(17874-17-8)
• EPA Substance Registry System: 1-Cyclohexenyltrimethylsilane(17874-17-8)

Safety Data

• Hazardous Substances Data: 17874-17-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 930-66-5 1-chlorocyclohexene 
• 108-94-1 cyclohexanone 
• 2044-08-8 1-bromocyclohex-1-ene 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 822-67-3 Cyclohex-2-enol 
• 474834-45-2 2-chloro-3-(ethoxymethoxy)cyclohexene 
• 930-68-7 cyclohexenone 
• 3400-88-2 2-chlorocyclohex-2-en-1-one 
• 6498-39-1 2-chlorocyclohex-2-en-1-ol 
• 5401-62-7 1,2-dibromocyclohexane 
• 115142-91-1 6-(trimethylsilyl)-5-hexyn-1-yl p-toluenesulfonate 
• 103437-52-1 6-trimethylsilanyl-hex-5-yn-1-ol 
• 928-90-5 5-hexyl-1-ol 

Downstream Products

• 18631-68-0 3-methyl-2,3,4,5,6,7-hexahydro-inden-1-one 
• 71352-18-6 2-Trimethylsilanyl-cyclohex-2-enol 
• 92120-25-7 ((1R,2S)-2-Chloro-1-methoxy-cyclohexyl)-trimethyl-silane 
• 92120-24-6 r-1-chloro-t-2-methoxy-1-trimethylsilylcyclohexane 
• 71559-38-1 t-1-iodo-c-2-methoxy-r-1-trimethylsilylcyclohexane 
• 92120-22-4 ((1R,2S)-2-Bromo-1-methoxy-cyclohexyl)-trimethyl-silane 
• 92120-21-3 t-2-methoxy-r-1-bromo-1-trimethylsilylcyclohexane 
• 18938-05-1 (4R*,9S*,10S*)-tricyclo<8.4.0.0^4,9>tetradec-1(2)-en-3-one 
• 106476-87-3 1-(1-cyclohexenyl)-2-(1-cyclohexenyl)ethanone 
• 144709-79-5 1-(2-trimethylsilyl-2-cyclohexenyl)-2-(1-cyclohexenyl)ethanone 
• 144709-78-4 1-(2-cyclohexenyl)-2-(1-cyclohexenyl)ethanone 
• 91897-80-2 1-(1'-cyclohexenyl)-2-buten-1-one 
• 109272-43-7 o-iodophenyl 1-cyclohexenyl ketone 
• 144709-75-1 1-(1-cyclohexenyl)-2-cyclopentylideneethanone 

Relevant articles and documents

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Preparation of Functionalized Acylsilanes by Diol Cleavage of Cyclic 1,2-Dihydroxysilanes

We report a study on diol cleavage of cyclic 1,2-dihydroxysilanes for the preparation of functionalized acylsilanes. Sodium periodate turned out to be an efficient reagent for this transformation, resulting in good to excellent yields. The method is chara

Preparation of amino substituted cyclic vinylsilanes by Wurtz-Fittig procedure

The Wurtz-Fittig method of silylation of simple vinyl halides to vinylsilanes is extended to aminosubstituted vinyl halides. 2-Halo-3-morpholinylcycloalkenes can be silylated to the corresponding 2-trimethylsilyl-3-morpholinyl-1-cycloalkenes using excess of chlorotrimethylsilane and sodium in dioxane solvent without significant cleavage of C-N-morpholinyl bond under these metal reduction conditions. Similar success was not achieved with piperidinyl derivatives.

Generation and Solution-phase Behaviour of Some 2-Halogeno-1,3-ring-fused Cyclopropenes

The title cyclopropenes 2b are readily formed by reaction of ring-fused β-silylated-gem-dihalogenocyclopropanes of the general type 1b with tetrabutylammonium fluoride in tetrahydrofuran solution.Those halogenocyclopropenes 2b which are fused to a seven-