144712-80-1

Basic information

• Product Name: syn-4,4-dimethyl-1-phenylpentane-1,3-diol
• CAS NO: 144712-80-1
• Molecular Weight: 208.301
• Mol File: 144712-80-1.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: syn-4,4-dimethyl-1-phenylpentane-1,3-diol(CAS DataBase Reference)
• NIST Chemistry Reference: syn-4,4-dimethyl-1-phenylpentane-1,3-diol(144712-80-1)
• EPA Substance Registry System: syn-4,4-dimethyl-1-phenylpentane-1,3-diol(144712-80-1)

Safety Data

• Hazardous Substances Data: 144712-80-1(Hazardous Substances Data)

Upstream product

• 13988-67-5 benzoylpivaloylmethane 
• 42052-52-8 1-hydroxy-4,4-dimethyl-1-phenylpentan-3-one 
• 67210-34-8 1-phenyl-2-phenylsulfanyl-ethanol 
• 630-19-3 pivalaldehyde 
• 98-86-2 acetophenone 
• 3282-30-2 pivaloyl chloride 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 96-09-3 styrene oxide 
• 80926-17-6 3-hydroxy-1-phenyl-4,4-dimethyl-pentan-1-one 
• 100-52-7 benzaldehyde 
• 75-97-8 3,3-dimethyl-butan-2-one 
• 538-44-3 4,4-dimethyl-1-phenyl-1-penten-3-one 

Relevant articles and documents

Reduction of β-hydroxyketones by Sml2/H2O/ Et3N

(Chemical Equation Presented) Reduction of a series of β- hydroxyketones by Sml2/H2O/Et3N provided 1,3-diols in quantitative yields. The reactions were exceedingly clean with no byproduct formation, negating the need for f

Solvent-dependent diastereoselectivities in reductions of β-hydroxyketones by Sml2

The reductions of a series of β-hydroxyketones by Sml2 were examined in THF, DME, and CH3CN using methanol as a proton source. Reductions in THF and DME typically lead to the syn diastereomer with DME providing higher diastereoselect

An especially convenient stereoselective reduction of β-hydroxy ketones to anti 1,3 diols using samarium diiodide

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