1448179-36-9Relevant articles and documents
Syntheses and crystal structures of two new complexes based on R-isophthalate (R = -CH3 or -OCH3) and bis(imidazole) Co-ligand
Qin, Jian-Hua,Wang, Jian-Ge,Zhao, Ke-Yan,Hu, Yue
, p. 647 - 651 (2013)
Two new complexes, [Co(CH3-ip)(biim-5)]n (1) and [Co(CH3O-ip)(biim-5)]n (2) (CH3-H2ip = 5-methylisophthalate, CH3O-H2ip = 5- methoxyisophthalate, biim-5 = 1,5-bis(imidazole)pentane), have been synthesized via hydrothermal reactions and characterized by elemental analysis and single-crystal X-ray analysis. Complex 1 belongs to the monoclinic system, P2(1)/c space group, a = 9.464(2) A, b = 14.567(4) A, c = 15.206(4) A, β = 102.369(2)°, F (000) = 916, R1 = 0.0701, wR2 = 0.1831; complex 2 belongs to the monoclinic system, P2(1)/c space group, a = 9.5922(17) A, b = 15.231(3) A, c = 16.3797(19) A, β = 122.638(7)°, F (000) = 948, R1 = 0.0466, wR2 = 0.1188. In the two complexes, CH3-ip and CH 3O-ip both adopt bis-monodentate bridging modes to link neighboring Co(II) ions to form 1D chains, which are further across-linked by biim-5 ligands to generate 2D (4,4) rectangular grid layers. These identical 2D single nets are interlocked with each other and form an interesting threefold parallel interpenetrated architecture. Copyright Taylor and Francis Group, LLC.