145428-83-7Relevant articles and documents
Synthesis of silylated alkylboronic acids and esters via hydroboration of allylic and vinylic trimethylsilanes
Cytarska,Kaczanowska,Zaidlewicz
, p. 1587 - 1594 (2008/09/18)
Representative allylic trimethylsilanes and isopropenyltrimethylsilane were hydroborated with dichloroborane, and the products were transformed into the corresponding ssor γ-trimethylsilylboronates. Synthesis of 2-trimethylsilylethylboronic acid and its diethyl ester via hydroboration of trimethylvinylsilane with diisopinocampheylborane, followed by liberation of α-pinene is described.