145838-91-1

Basic information

• Product Name: 1-diazo-4-phenylhexane-2,5-dione
• Synonyms: 1-diazo-4-phenylhexane-2,5-dione
• CAS NO: 145838-91-1
• Molecular Weight: 216.239
• Mol File: 145838-91-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-diazo-4-phenylhexane-2,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-diazo-4-phenylhexane-2,5-dione(145838-91-1)
• EPA Substance Registry System: 1-diazo-4-phenylhexane-2,5-dione(145838-91-1)

Safety Data

• Hazardous Substances Data: 145838-91-1(Hazardous Substances Data)

Upstream product

• 103-79-7 1-phenyl-acetone 
• 63795-90-4 3-phenyl-4-oxopentanoic acid ethyl ester 
• 186581-53-3 diazomethane 
• 6049-50-9 4-Oxo-3-phenylpentanoic acid 

Relevant articles and documents

Chemoselectivity of rhodium carbenoids. A comparison of the selectivity for O-H insertion reactions or carbonyl ylide formation versus aliphatic and aromatic C-H insertion and cyclopropanation

A range of diazocarbonyl compounds 1-9 containing two different functional groups has been prepared, and their rhodium(II) catalysed decomposition studied as a means of probing the chemoselectivity of carbenoid intermediates. The results indicate that wereas O-H insertion reactions predominate over cyclopropanation and aromatic insertion reactions, carbonyl ylide formation vs other competing processes is more finely balanced, and is catalyst dependent.