146174-68-7Relevant articles and documents
PHOTOLYTIC GENERATION OF KETONES FROM 6-PHENANTHRIDINYLMETHYL ETHERS OF SECONDARY ALCOHOLS
Rukachaisirikul, Vatcharin,Hoffmann, Reinhard W.
, p. 10563 - 10568 (2007/10/02)
Ketones are generated by photolysis (>320 nm) of 6-phenanthridinylmethyl ethers of secondary alcohols.The 6-phenanthridinylmethyl group may therefore be utilized as a latent carbonyl function, especially as the 6-phenanthridinyl-methyl group is chemically inert toward hydroboration, Grignard additions, LiAlH4-reduction, bromination or ozonolysis at other parts of the molecule.