40484-36-4Relevant articles and documents
Controlling the isomerization rate of an azo-BF2 switch using aggregation
Qian, Hai,Wang, Yu-Ying,Guo, Dong-Sheng,Aprahamian, Ivan
supporting information, p. 1037 - 1040 (2017/05/15)
A novel visible-light activated azo-BF2 switch possessing a phenanthridinyl π-system has been synthesized, and its switching properties have been characterized as a function of concentration. The switch self-aggregates through π-π interactions, and the degree of aggregation modulates the Z → E thermal isomerization rate. This property allows for the active tuning of the thermal relaxation half-life of the same switch from seconds to days.
SYNTHESE DANS LA SERIE DES PHENANTHRIDINES. IV. PREPARATION DE NOUVEAUX RADIOPROTECTEURS A MOTIF PHENANTHRIDINE
Lion, Claude,Boukou-Poba, Jean-Paul,Charvy, Claude
, p. 169 - 174 (2007/10/02)
New phenanthridines substituted in the 6-position by a β-aminoethylthiol chain have been synthesized.These new products are easily obtained from 6-methylphenanthridine by a Mannich reaction or from 6-bromophenanthridine by substitution.From the 6-carboxaldehydophenanthridine and the β-aminoethylthiol, the corresponding thiazolidine or imine are obtained.These compounds are likely to be new radioprotectors.