146604-63-9

Basic information

• Product Name: 2-Propenoic acid, 3-phenyl-, 2-hydroxyethyl ester, (E)-
• CAS NO: 146604-63-9
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 146604-63-9.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-phenyl-, 2-hydroxyethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-phenyl-, 2-hydroxyethyl ester, (E)-(146604-63-9)
• EPA Substance Registry System: 2-Propenoic acid, 3-phenyl-, 2-hydroxyethyl ester, (E)-(146604-63-9)

Safety Data

• Hazardous Substances Data: 146604-63-9(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 818-61-1 2-hydroxyethyl acrylate 
• 140-10-3 (E)-3-phenylacrylic acid 
• 107-21-1 ethylene glycol 
• 1115400-44-6 trans-cinnamic acid-(2-chloro-ethyl ester) 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 83977-12-2 2-((E)-Styryl)-[1,3]dioxolane 
• 104-55-2 3-phenyl-propenal 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 149794-30-9 (2E-3-phenyl-prop-2-enonyl)-phosphonic acid dimethyl ester 
• 102-92-1 Cinnamoyl chloride 
• 14371-10-9 (E)-3-phenylpropenal 
• 4360-66-1 2-(bromomethylidene)-1,3-dioxolane 

Downstream Products

• 1353586-32-9 C₁₈H₁₄N₂O₄S 

Relevant articles and documents

Rhutenium-Catalyzed Oxidation of Cyclic Acetals with tert-Butyl Hydroperoxide. A Facile Synthesis of Glycol Monoesters

The ruthenium-catalyzed oxidation of cyclic acetals with tert-butyl hydroperoxide under mild conditions gives the corresponding glycol monoesters efficiently.The present oxidation reaction provides a useful method for the synthesis of glycol monoesters from 1-alkenes by combination with palladium-catalyzed acetalization of 1-alkenes.

Palladium on Carbon-Catalyzed Chemoselective Oxygen Oxidation of Aromatic Acetals

The development of an unprecedented chemoselective transformation has contributed to forming a novel synthetic process for target molecules. Chemoselective oxidation of aromatic acetals has been accomplished using a reusable palladium on carbon catalyst under atmospheric oxygen conditions to form ester derivatives with tolerance of aliphatic acetals and ketals.

Interfacially cross-linked reverse micelles as soluble support for palladium nanoparticle catalysts

Reverse micelles (RM) were formed in heptane/CHCl3 with a surfactant carrying the triallylammonium (=triprop-2-en-1-ylammonium) head group (Scheme). Photo-cross-linking with dithiothreitol (=rel-(2R,3R)-1,4- dimercaptobutane-2,3-diol; DTT) captured the RMs and afforded organic, soluble nanoparticles in a one-step reaction. Similar to dendrimers, the cross-linked reverse micelles could encapsulate palladium nanoparticles within their hydrophilic cores and protect them in catalytic reactions. Good to excellent yields were obtained in the Heck coupling of a range of alkyl acrylates (=alkyl prop-2-enoates) and iodobenzenes (Tables 1 and 2). The catalytic activity of the palladium nanoparticles was maintained in several repeated runs.