1469-83-6

Basic information

• Product Name: 1-Phenylcyclobutanecarbaldehyde
• Synonyms: 1-Phenylcyclobutanecarbaldehyde;1-Phenylcyclobutanecarboxaldehyde
• CAS NO: 1469-83-6
• Molecular Formula: C₁₁H₁₂O
• Molecular Weight: 160.21
• Mol File: 1469-83-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 95-97 °C
• Appearance: /
• Density: 1.142±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-Phenylcyclobutanecarbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenylcyclobutanecarbaldehyde(1469-83-6)
• EPA Substance Registry System: 1-Phenylcyclobutanecarbaldehyde(1469-83-6)

Safety Data

• Hazardous Substances Data: 1469-83-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 38, p. 36, 1973 DOI: 10.1021/jo00941a008

Upstream product

• 109-64-8 1,3-dibromo-propane 
• 26939-22-0 2-benzyl-4,4,6-trimethyl-5,6-dihydro-4H-[1,3]oxazine 
• 37828-19-6 1-(phenyl)cyclobutane-1-carboxylic acid 
• 140-29-4 phenylacetonitrile 
• 14377-68-5 1-phenylcyclobutanecarbonitrile 
• 109-94-4 formic acid ethyl ester 
• 4620-67-1 1-phenylcyclobutane-carbonyl chloride 
• 70775-57-4 (1-phenylcyclobutyl)methanol 

Downstream Products

• 1198-34-1 2-Phenylcyclopentanone 
• 166877-81-2 1-methoxy-2-(1-phenylcyclobutyl)ethene 
• 957107-63-0 C₁₅H₁₈O₂ 
• 37828-19-6 1-(phenyl)cyclobutane-1-carboxylic acid 
• 1026951-05-2 2-(Diphenyl-phosphinoyl)-2-methoxy-1-(1-phenyl-cyclobutyl)-ethanol 
• 1378974-39-0 (1-ethynylcyclobutyl)benzene 
• 1016970-17-4 1-(1-phenylcyclobutyl)prop-2-ynyl acetate 
• 70775-57-4 (1-phenylcyclobutyl)methanol 

Relevant articles and documents

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Biarylphosphonite gold(I) complexes as superior catalysts for oxidative cyclization of propynyl arenes into indan-2-ones

Striking gold: A series of variously functionalized propynyl arenes was smoothly converted into indan-2-ones by a new gold(I)-catalyzed oxidative cyclization process. [LAu]NTf2 (Tf=trifluoromethanesulfonyl) is a superior catalyst both in terms of yield and kinetics for the present transformation. Copyright

Gold-catalyzed double migration-benzannulation cascade toward naphthalenes

(Chemical Equation Presented) A novel gold(I)-catalyzed cycloisomerization of propargylic esters leading to unsymmetrically substituted naphthalenes has been developed. This cascade reaction involves an unprecedented tandem sequence of 1,3- and 1,2-migration of two different migrating groups. It is believed that this transformation likely proceeds via the formation of 1,3-diene intermediate or its precursor, which upon cyclization and aromatization steps transforms into the naphthalene core. 2008 American Chemical Society.