146937-36-2Relevant articles and documents
Asymmetric synthesis of syn- and anti-α-deuterio-β3- phenylalanine derivatives
Davies, Stephen G.,Foster, Emma M.,McIntosh, Catherine R.,Roberts, Paul M.,Rosser, Timothy E.,Smith, Andrew D.,Thomson, James E.
, p. 1035 - 1050 (2011/10/04)
The conjugate addition of lithium (S)-N-benzyl-N-(α-methylbenzyl) amide to a range of aryl substituted tert-butyl cinnamate esters followed by reaction of the resultant lithium β-amino enolates with D2O provides access to anti configured α-deut
Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
Bull, Steven D.,Davies, Stephen G.,Fenton, Carry,Mulvaney, Andrew W.,Shyam Prasad,Smith, Andrew D.
, p. 3765 - 3774 (2007/10/03)
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. The Royal Society of Chemistry 2000.
Synthesis of β-amino esters by the conjugate addition of nitrogen nucleophiles to α,β-unsaturated esters having chiral p-tolylsulfinyl groups
Matsuyama, Haruo,Itoh, Nobuhiro,Yoshida, Masato,Kamigata, Nobumasa,Sasaki, Sigeru,Iyoda, Masahiko
, p. 375 - 376 (2007/10/03)
The conjugate addition of nitrogen nucleophiles to t-butyl (E)-2-(p-tolylsulfinyl)cinnamates (1) afforded the corresponding chiral β-amino esters, which are important building blocks for synthesis of biologically active polyamine alkaloids. The diastereos