14773-53-6Relevant articles and documents
Hydropyridylation of Olefins by Intramolecular Minisci Reaction
Bordi, Samuele,Starr, Jeremy T.
, p. 2290 - 2293 (2017)
An unprecedented cheap, mild and easy methodology for an intramolecular Minisci reaction based on a hydrogen atom transfer (HAT) initiated hydrofunctionalization of olefins was developed. The method is suitable for the construction of unusual dihydropyrano-pyridine and 1,2,3,4-tetrahydronaphthiridine structures and, unlike most similar reactions, does not require exclusion of air from the reaction medium.
Photosolvolysis reactions of 3-alkoxypyridinium tetrafluoroborate salts
Penkett, Clive S.,Simpson, Iain D.
, p. 6183 - 6204 (2007/10/03)
Irradiation of a series of 3-alkoxypyridinium tetrafluoroborate salts in alcohol solution resulted in the formation of cyclopentenone ketals by diastereoselective incorporation of the alcohol solvent under the basic conditions of the photolysis reaction. In a second series of photochemical reactions, the same 3-alkoxypyridinium salts were irradiated in water to yield β-hydroxycyclopentanones stereoselectively.
