1492057-01-8

Basic information

• Product Name: (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol
• Synonyms: (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol
• CAS NO: 1492057-01-8
• Molecular Weight: 368.591
• Mol File: 1492057-01-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol(1492057-01-8)
• EPA Substance Registry System: (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol(1492057-01-8)

Safety Data

• Hazardous Substances Data: 1492057-01-8(Hazardous Substances Data)

Upstream product

• 13201-46-2 2-methylbut-2-enoic acid 
• 80-59-1 Tiglic acid 
• 1492056-99-1 (S)-tert-butyl 3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-enoate 
• 1492056-88-8 (S)-tert-butyl 3-(hydroxymethyl)-3-methylpent-4-enoate 
• 1492056-85-5 (S)-tert-butyl 3-((R)-4-isopropyl-2-oxooxazolidine-3-carbonyl)-3-methylpent-4-enoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 35660-94-7 (E)-2-methylbut-2-enoyl chloride 

Downstream Products

• 1020108-55-7 (3S)-3-ethenyl-1-(4-methoxyphenyl)-3,7-dimethyloct-6-en-2-ol 
• 1020108-56-8 (3S)-3-ethenyl-1-(4-methoxyphenyl)-3,7-dimethyloct-6-en-2-yl methanesulfonate 
• 1020108-60-4 (2S)-2-[(E)-2-(4-methoxyphenyl)ethenyl]-2,6-dimethylhept-5-enal 
• 1492057-02-9 (S)-((2-(2-bromoethyl)-2-methylbut-3-en-1-yl)oxy)(tert-butyl)diphenylsilane 
• 1492057-03-0 C₂₇H₃₈OSi 
• 17015-63-3 (S,E)-1-(3,7-dimethyl-3-vinylocta-1,6-dien-1-yl)-4-methoxybenzene 
• 17015-60-0 bakuchiol 
• 1492057-09-6 C₃₄H₄₄O₂Si 
• 1020108-59-1 (2S)-2-[(E)-2-(4-methoxyphenyl)ethenyl]-2,6-dimethylhept-5-en-1-ol 
• 1020108-61-5 (R,E)-1-(3,7-dimethyl-3-vinylocta-1,6-dien-1-yl)-4-methoxybenzene 
• 1020108-62-6 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol 

Relevant articles and documents

A natural product scurfpea and its enantiomer asymmetric synthetic method

The invention discloses a natural product fructus psoraleae phenol and an asymmetric synthesis method of an enantiomer thereof, belongs to the field of chemical synthesis, relates to a chemical synthesis technology, and particularly relates to a natural product Bakuchoil with optical activity and a preparation method of the enantiomer ent-Bakuchoil of the natural product. According to the method disclosed by the invention, tiglic acid and tert-butyl acetate which are easily available industrially are taken as initial raw materials to synthesize a key midbody compound 11, subsequently based of the key midbody, the natural product Bakuchoil with optical activity and the enantiomer ent-Bakuchoil thereof can be respectively synthesized by two short synthesis strategies. The method disclosed by the invention is simple to operate, convenient in separation operation, high in yield and good in selectivity, and the used reagents are all common reagents.