1493-86-3Relevant articles and documents
From C1 to C3: Copper-Catalyzed gem-Bis(trifluoromethyl)olefination of α-Diazo Esters with TMSCF3
Hu, Jinbo,Hu, Mingyou,Liu, Qinghe,Ni, Chuanfa,Pan, Shitao,Wang, Qian,Xie, Qiqiang
, p. 8507 - 8511 (2020)
A Cu-catalyzed gem-bis(trifluoromethyl)olefination of α-diazo esters, using TMSCF3 as the only fluorocarbon source, has been developed and provides an exquisite method to access gem-bis(trifluoromethyl)alkenes. This unprecedented olefination pr
Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3
Jin, Guanyi,Zhang, Xuxue,Fu, Dan,Dai, Wenpeng,Cao, Song
, p. 7892 - 7899 (2015/09/15)
A direct and efficient approach for the trifluoromethylation and pentafluoroethylation of 1,1-diaryl-2,2-difluoroethenes with TMSCF3 and TMSCF2CF3 in the presence of TBAF was developed. The reactions proceeded smoothly und
On the reactions of trifluorovinylsilanes with aromatic ketones - Expected and some unexpected results
Kirij,Dontsova,Pavlenko,Yagupolskii,Tyrra,Naumann
experimental part, p. 184 - 189 (2010/04/30)
The reactions of aromatic ketones with trialkyl(trifluorovinyl)silanes in the presence of fluoride ions were studied. The conditions for the selective addition of trialkyl(trifluorovinyl)silanes to the carbonyl function of aromatic ketones in the presence
