1501945-26-1Relevant articles and documents
Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates
Park, Nathaniel H.,Teverovskiy, Georgiy,Buchwald, Stephen L.
supporting information, p. 220 - 223 (2014/01/23)
A new air-stable nickel precatalyst for C-N cross-coupling is reported. The developed catalyst system displays a greatly improved substrate scope for C-N bond formation to include both a wide range of aryl and heteroaryl electrophiles and aryl, heteroaryl, and alkylamines. The catalyst system is also compatible with a weak base, allowing the amination of substrates containing base-sensitive functional groups.
