15023-67-3

Basic information

• Product Name: 4-nitrophenyl 4-methylbenzoate
• Synonyms: 4-nitrophenyl 4-methylbenzoate
• CAS NO: 15023-67-3
• Molecular Formula: C₁₄H₁₁NO₄
• Molecular Weight: 257.24144
• Mol File: 15023-67-3.mol
• Article Data: 23

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-nitrophenyl 4-methylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitrophenyl 4-methylbenzoate(15023-67-3)
• EPA Substance Registry System: 4-nitrophenyl 4-methylbenzoate(15023-67-3)

Safety Data

• Hazardous Substances Data: 15023-67-3(Hazardous Substances Data)

Upstream product

• 100-02-7 4-nitro-phenol 
• 99-94-5 p-Toluic acid 
• 7693-46-1 4-Nitrophenyl chloroformate 
• 830-03-5 4-nitrophenol acetate 
• 589-18-4 4-Methylbenzyl alcohol 
• 104-87-0 4-methyl-benzaldehyde 
• 874-60-2 4-methyl-benzoyl chloride 
• 824-78-2 4-nitrophenol sodium salt 
• 201230-82-2 carbon monoxide 
• 624-31-7 4-tolyl iodide 

Downstream Products

• 100-02-7 4-nitro-phenol 
• 121106-39-6 N-dodecyl-4-methylbenzamide 
• 99-94-5 p-Toluic acid 
• 38597-13-6 4-Bromomethyl-benzoic acid 4-nitro-phenyl ester 
• 94-08-6 4-methylbenzoic acid ethyl ester 
• 14609-74-6 p-nitrophenolate 
• 15023-58-2 4-chlorophenyl 4-methylbenzoate 
• 1900-85-2 phenyl p-methylbenzoate 
• 5118-31-0 4-methylbenzoate 
• 501660-63-5 [2-(4-methyl-benzoylamino)-acetylamino]-acetic acid 
• 3619-22-5 p-toluic hydrazide 
• 13707-23-8 N-(4-methylbenzoyl)piperidine 
• 63833-44-3 morpholino(p-tolyl)methanone 
• 111752-26-2 piperazin-1-yl(p-tolyl)methanone 

Relevant articles and documents

Sodium cyanide-promoted copper-catalysed aerobic oxidative synthesis of esters from aldehydes

A simple and efficient copper-catalysed procedure for oxidative esterification of aldehydes with alcohols and phenols mediated by sodium cyanide, using air as a clean oxidant, is described. A variety of aromatic aldehydes and structurally different alcohols and phenols reacted efficiently, and the product esters were obtained in good to excellent yields under normal atmospheric and solvent-free conditions.

Alkaline Hydrolysis of 4-Nitrophenyl X-Substituted-Benzoates Revisited: New Insights from Yukawa–Tsuno Equation

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Olefins from biomass feedstocks: Catalytic ester decarbonylation and tandem Heck-type coupling

With the goal of avoiding the need for anhydride additives, the catalytic decarbonylation of p-nitrophenylesters of aliphatic carboxylic acids to their corresponding olefins, including commodity monomers like styrene and acrylates, has been developed. The reaction is catalyzed by palladium complexes in the absence of added ligands and is promoted by alkali/alkaline-earth metal halides. Combination of catalytic decarbonylation and Heck-type coupling with aryl esters in a single pot process demonstrates the viability of employing a carboxylic acid as a "masked olefin" in synthetic processes. This journal is