150618-24-9

Basic information

• Product Name: Ethyl (Z)-4,4,5,5,6,6,6-heptafluoro-3-benzylamino-2-hexenoate
• Synonyms: Ethyl (Z)-4,4,5,5,6,6,6-heptafluoro-3-benzylamino-2-hexenoate
• CAS NO: 150618-24-9
• Molecular Weight: 373.27
• Mol File: 150618-24-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethyl (Z)-4,4,5,5,6,6,6-heptafluoro-3-benzylamino-2-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl (Z)-4,4,5,5,6,6,6-heptafluoro-3-benzylamino-2-hexenoate(150618-24-9)
• EPA Substance Registry System: Ethyl (Z)-4,4,5,5,6,6,6-heptafluoro-3-benzylamino-2-hexenoate(150618-24-9)

Safety Data

• Hazardous Substances Data: 150618-24-9(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 336-62-9 (2,2,3,3,4,4,4-heptafluorobutanoyl)acetic acid ethyl ester 

Downstream Products

• 178381-05-0 4,4,5,5,6,6,6-Heptafluoro-3-{[1-phenyl-meth-(E)-ylidene]-amino}-hexanoic acid ethyl ester 

Relevant articles and documents

A convenient synthesis of perfluoroalkylated enamines and vinyl phosphonates

The reaction of fluoroalkynes with ammonia and benzylamine gave perfluoroalkylated enamines predominantly as the Z isomer, which were hydrogenated with palladium on carbon to afford perfluoroalkylated β-amino acids in good yield.The reaction of fluoroalky

Transamination of Fluorinated β-Keto Carboxylic Esters. A Biomimetic Approach to β-Polyfluoroalkyl-β-amino Acids.

The base-catalyzed isomerization of N-benzylimines (or enamines) of β-polyfluoroalkyl-β-ketocarboxylic esters cleanly affords the N-benzylidene derivatives of β-polyfluoro-β-aminocarboxylic esters which are hydrolyzed to corresponding amino acids in high overall yields.