15137-12-9

Basic information

• Product Name: mer-Rh(C6H5PEt2)3Cl3
• CAS NO: 15137-12-9
• Molecular Weight: 707.873
• Mol File: 15137-12-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: mer-Rh(C6H5PEt2)3Cl3(CAS DataBase Reference)
• NIST Chemistry Reference: mer-Rh(C6H5PEt2)3Cl3(15137-12-9)
• EPA Substance Registry System: mer-Rh(C6H5PEt2)3Cl3(15137-12-9)

Safety Data

• Hazardous Substances Data: 15137-12-9(Hazardous Substances Data)

Upstream product

• 15137-12-9 mer-Rh(C6H5PEt2)3Cl3 
• 95348-88-2 (Rh₂Cl₆(P(C₂H₅)2(C₆H₅))3) 
• 1605-53-4 diethyl-phenyl-phosphine 
• 124-38-9 carbon dioxide 

Downstream Products

• 25504-23-8 RhCl(PEt₂Ph₃)3 
• 15137-12-9 fac-Rh(C₆H₅PEt₂)3Cl₃ 
• 95348-90-6 ((P(C₂H₅)2(C₆H₅))2ClRhCl₃RhCl(P(C₂H₅)2(C₆H₅))2)⁽¹⁺⁾*(B(C₆H₅)4)^(1-) 
• 95348-91-7 (RhCl₃(P(C₂H₅)2C₆H₅)2(H₂O)) 
• 95348-88-2 (Rh₂Cl₆(P(C₂H₅)2(C₆H₅))3) 

Relevant articles and documents

Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. the First Evidence of CO2 Insertion into the O-O Bond of Rh(η2-O2) Complexes

Extended labeling experiments have shown that formation of rhodium peroxocarbonate from CO2 and [RhCl(η2-O2(P)3] (P is PEt2Ph or PEtPh2) proceeds through O-O bond cleavage and CO2 insertion. O-transfer to ancillary phosphine ligand to give R3P=O selectively (>85%) involves the Rh-linked O atom of the peroxo group of RhCl(CO4)(P)3.