151693-59-3

Basic information

• Product Name: (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfonyl-cyclohexane-1,2,3,4-tetraol
• Synonyms: (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfonyl-cyclohexane-1,2,3,4-tetraol
• CAS NO: 151693-59-3
• Molecular Weight: 510.608
• Mol File: 151693-59-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfonyl-cyclohexane-1,2,3,4-tetraol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfonyl-cyclohexane-1,2,3,4-tetraol(151693-59-3)
• EPA Substance Registry System: (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfonyl-cyclohexane-1,2,3,4-tetraol(151693-59-3)

Safety Data

• Hazardous Substances Data: 151693-59-3(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 151693-57-1 (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O-cyclohexylidenecyclohexane-1,2,3,4-tetraol 
• 135735-91-0 (1R,2R,3S,4R,5R)-3-O-Benzyl-5-benzyloxymethyl-1,2-O-cyclohexylidene-cyclohexan-1,2,3,4-tetraol 
• 161484-58-8 (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethyl-1,2-O,O-sulfinyl-cyclohexane-1,2,3,4-tetraol 
• 151693-58-2 (1R,2R,3S,4R,5R)-3,4-di-O-benzyl-5-benzyloxymethylcyclohexane-1,2,3,4-tetraol 

Downstream Products

• 151693-64-0 (1R,2R,3R,4R)-1-O-acetyl-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 151693-61-7 (1S,2R,3R,4R)-1-O-benzoyl-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 161596-04-9 (1R,2R,3R,4R)-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 161596-05-0 (1S,2R,3R,4R)-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 151765-53-6 (1S,2R,3S,4S,5R,6R)-3-O-acetyl-4,5-di-O-benzyl-6-benzyloxymethyl-1,2-epoxycyclohexane-3,4,5-triol 
• 151693-65-1 (1R,2S,3S,4S,5R,6R)-3-O-acetyl-4,5-di-O-benzyl-6-benzyloxymethyl-1,2-epoxycyclohexane-3,4,5-triol 
• 161484-59-9 (1R,2R,3R,4S,6R)-3-O-acetyl-1,2-di-O-benzyl-6-benzyloxymethyl-4-iodocyclohexane-1,2,3-triol 
• 161596-08-3 (1R,2S,3R,4S)-2,3-di-O-benzyl-4-benzyloxymethyl-1-(O-tert-butyldimethylsilyl)cyclohex-5-ene-1,2,3-triol 
• 161484-60-2 (1S,2S,3R,4S)-2,3-di-O-benzyl-5-benzyloxymethyl-1-O-tert-butyldimethylsilylcyclohex-5-ene-1,2,3-triol 
• 161596-09-4 (1R,2R,3S,4R,5R,6R)-3,4-di-O-benzyl-5-benzyloxymethyl-2-O-tert-butyldimethylsilyl-7-oxabicyclo<4.1.0>heptane-2,3,4-triol 
• 151765-54-7 (1S,2S,3R,4R,5R,6R)-3,4-bis(benzyloxy)-5-((benzyloxy)methyl)-7-oxabicyclo[4.1.0]heptan-2-ol 
• 151693-63-9 (1S,2R,3R,4R,5R,6R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 161596-07-2 (1R,2S,3R,4R,5R,6S)-3,4-Bis-benzyloxy-5-benzyloxymethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 151765-52-5 (1R,2R,3R,4R,5R,6S)-3,4-Bis-benzyloxy-5-benzyloxymethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 

Relevant articles and documents

(-)-Quinic Acid in Organic Synthesis. Part 4. Syntheses of Cyclophellitol and its (1R,6S)-, (2S)-, (1R,2S,6S)-Diastereoisomers

Cyclophellitol 1 and its (1R,6S)-, (2S)-, (1R,2S,6S)-diastereoisomers 2, 3 and 4 are constructed from quinic acid involving the following key steps: regioselective cyclic sulfate ring opening, regiospecific oxidative elimination and an epoxidation.Diastereoisomers 1, 2, 3 and 4 are characterized as their corresponding tetraacetates 5, 6, 7 and 8.