151693-61-7Relevant articles and documents
Stereoselective synthesis of (-)-ara-cyclohexenyl-adenine
Horváth, András,Ruttens, Bart,Herdewijn, Piet
, p. 3621 - 3623 (2008/02/02)
A stereoselective synthesis leading to (-)-ara-cyclohexenyl-adenine is described. The synthesis starts from methyl-α-d-glucopyranose and involves an isomerization step, selective protection/deprotection chemistry, a Ferrier rearrangement and a Mitsunobu r
(-)-Quinic Acid in Organic Synthesis. Part 4. Syntheses of Cyclophellitol and its (1R,6S)-, (2S)-, (1R,2S,6S)-Diastereoisomers
Shing, Tony K. M.,Tai, Vincent W.-F.
, p. 2017 - 2026 (2007/10/02)
Cyclophellitol 1 and its (1R,6S)-, (2S)-, (1R,2S,6S)-diastereoisomers 2, 3 and 4 are constructed from quinic acid involving the following key steps: regioselective cyclic sulfate ring opening, regiospecific oxidative elimination and an epoxidation.Diastereoisomers 1, 2, 3 and 4 are characterized as their corresponding tetraacetates 5, 6, 7 and 8.