151767-37-2

Basic information

• Product Name: thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside
• Synonyms: thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside
• CAS NO: 151767-37-2
• Molecular Weight: 382.434
• Mol File: 151767-37-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside(151767-37-2)
• EPA Substance Registry System: thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside(151767-37-2)

Safety Data

• Hazardous Substances Data: 151767-37-2(Hazardous Substances Data)

Upstream product

• 2873-29-2 D-glucal triacetate 
• 88580-20-5 3,4,6-tri-O-acetyl-2-deoxy-α-D-arabino-hexopyranosyl chloride 
• 108-98-5 thiophenol 

Downstream Products

• 104016-87-7 phenylsulfonyl 3,4,6-tri-O-t-butyldimethylsilyl-2-deoxy-α-D-arabino-hexopyranoside 
• 104039-25-0 phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-β-D-arabino-hexopyranoside 
• 515821-31-5 phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside 
• 104017-04-1 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanone 
• 104016-91-3 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanol 
• 104017-13-2 (2R,3R,4R,6R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran 
• 104017-14-3 (2R,3R,4R,6S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran 
• 104017-13-2 (2R,3R,4R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran 
• 104017-21-2 C₃₀H₅₇⁽²⁾HO₆SSi₃ 
• 105026-35-5 (2R,3S,4R)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 

Relevant articles and documents

Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t