515821-31-5

Basic information

• Product Name: phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside
• CAS NO: 515821-31-5
• Molecular Weight: 631.109
• Mol File: 515821-31-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside(515821-31-5)
• EPA Substance Registry System: phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside(515821-31-5)

Safety Data

• Hazardous Substances Data: 515821-31-5(Hazardous Substances Data)

Upstream product

• 104017-13-2 (2R,3R,4R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran 
• 108-98-5 thiophenol 
• 2873-29-2 D-glucal triacetate 
• 151767-37-2 thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside 
• 88580-20-5 3,4,6-tri-O-acetyl-2-deoxy-α-D-arabino-hexopyranosyl chloride 

Downstream Products

• 104039-26-1 [(2S,4R,5R,6R)-2-Benzenesulfonyl-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanone 
• 104016-99-1 [(4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((2S,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanone 
• 104016-96-8 [(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanone 
• 104017-04-1 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanone 
• 104017-02-9 (2R,4R,5R,6R)-2-Benzenesulfonyl-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 104017-01-8 (2S,4R,5R,6R)-2-Benzenesulfonyl-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 104051-21-0 [(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol 
• 104017-00-7 (2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-(hydroxy-phenyl-methyl)-tetrahydro-pyran-2-ol 
• 104016-91-3 [(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanol 
• 104017-23-4 3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol 
• 104016-91-3 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanol 
• 104017-09-6 [(2S,4R,5R,6R)-2-Benzenesulfonyl-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((4S,5R,6S)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanone 

Relevant articles and documents

Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t