15341-31-8

Basic information

• Product Name: (Z)-α-Nitrostilbene
• Synonyms: (Z)-α-Nitrostilbene;1,1′-[(1Z)-1-Nitro-1,2-ethenediyl]bis-benzene;CID 2818500;trans-α-Nitrostilbene;[(Z)-2-nitro-2-phenylethenyl]benzene
• CAS NO: 15341-31-8
• Molecular Formula: C₁₄H₁₁NO₂
• Molecular Weight: 225.24
• Mol File: 15341-31-8.mol
• Article Data: 13

Chemical Properties

• Appearance: white to beige/
• Storage Temp.: room temp
• Solubility: DMSO: soluble20mg/mL, clear
• CAS DataBase Reference: (Z)-α-Nitrostilbene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-α-Nitrostilbene(15341-31-8)
• EPA Substance Registry System: (Z)-α-Nitrostilbene(15341-31-8)

Safety Data

• Hazard Codes: Xn
• Statements: 22-51
• WGK Germany: 3
• Hazardous Substances Data: 15341-31-8(Hazardous Substances Data)

Upstream product

• 1689-71-0 2,3-diphenyloxirane 
• 645-49-8 cis-stilben 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 622-42-4 1-nitro-1-phenylmethane 
• 100-52-7 benzaldehyde 
• 7647-01-0 hydrogenchloride 
• 408353-60-6 1,2-diphenyl-2-methoxy-1-nitroethane 
• 67765-80-4 (+/-)-1,2-dinitro-1,2-diphenylethane 
• 124-41-4 sodium methylate 
• 588-59-0 stilbene 
• 110-89-4 piperidine 
• 64-17-5 ethanol 
• 13286-95-8 meso-1,2-dinitro-1,2-diphenylethane 
• 16906-54-0 trans-1,2-dinitrostilbene 

Downstream Products

• 622-42-4 1-nitro-1-phenylmethane 
• 2169-69-9 ethyl (E)-2-cyano-3-phenyl-2-propenoate 
• 1796-05-0 cis-1,2-dinitrostilbene 
• 107424-05-5 2-Acetyl-4-aci-nitro-3,4-diphenylbutansaeure-t-butylester 
• 33471-63-5 1,4,5-triphenyl-1H-1,2,3-triazole 
• 103549-15-1 N-(α'-nitro-bibenzyl-α-yl)-aniline 
• 22902-36-9 2,3-diphenylbenzo[4,5]imidazo[2,1-b]thiazole 
• 16576-23-1 1-benzoylisoquinoline 
• 5533-73-3 4,5-Diphenyl-1H-[1,2,3]triazole 
• 3274-66-6 ethyl 2,4,5-triphenyl-1H-pyrrole-3-carboxylate 
• 1397266-47-5 (1S,2R)-2-nitro-1,2-diphenylethyl ethanethioate 
• 123191-68-4 (+/-)-erythro-2-Amino-1,2-diphenylethanesulfonic acid 

Relevant articles and documents

DONOR PROPERTIES OF cis-DIPYRIDINETUNGSTEN TETRACARBONYL

-

Synthesis of Benzo[4,5]imidazo[2,1-b]thiazole by Copper(II)-Catalyzed Thioamination of Nitroalkene with 1H-Benzo[d]imidazole-2-thiol

A Copper(II)-catalyzed thioamination of β-nitroalkene with 1H-benzo[d]imidazole-2-thiol has been developed for the synthesis of benzo[4,5]imidazo[2,1-b]thiazole derivatives. A variety of N-fused benzoimidazothiazole derivatives are obtained in high yields through successive C?N and C?S bond formations. This protocol is also applicable to β-substituted β-nitroalkenes to afford 2,3-disubstituted benzoimidazothiazoles. (Figure presented.).

K2S2O8-mediated nitration of alkenes with NaNO2 and 2,2,6,6-tetramethylpiperidine-1-oxyl: Stereoselective synthesis of (E)-nitroalkenes

A transition-metal-free nitration of alkenes with NaNO2 in the presence of K2S2O8 and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) is developed. The transformation exhibits a broad substrate scope and good functional group tolerance, thus providing a new and expedient protocol for stereoselective synthesis of (E)-nitroalkenes with moderate to good yields. Moreover, the nitration processes of (E)- and (Z)-stilbene are also studied: even though the proportion of substrates is different, the E/Z ratio of the products is basically the same. Based upon experimental observations, a possible reaction mechanism is proposed.