1566-67-2

Basic information

• Product Name: Ethenol, 2-phenyl-,1-acetate, (1Z)-
• Synonyms: Ethenol,2-phenyl-, acetate, (1Z)- (9CI); Ethenol, 2-phenyl-, acetate, (Z)- (8CI);(Z)-Styryl acetate
• CAS NO: 1566-67-2
• Molecular Formula: C10H10 O2
• Molecular Weight: 162.188
• Mol File: 1566-67-2.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Ethenol, 2-phenyl-,1-acetate, (1Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethenol, 2-phenyl-,1-acetate, (1Z)-(1566-67-2)
• EPA Substance Registry System: Ethenol, 2-phenyl-,1-acetate, (1Z)-(1566-67-2)

Safety Data

• Hazardous Substances Data: 1566-67-2(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 62-38-4 phenylmercuric acetate 
• 603-35-0 triphenylphosphine 
• 62-38-4 phenylmercury(II)acetate 
• 64-19-7 acetic acid 
• 122-78-1 phenylacetaldehyde 
• 75-36-5 acetyl chloride 
• 60-12-8 2-phenylethanol 
• 536-74-3 phenylacetylene 
• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 108-24-7 acetic anhydride 
• 3375-31-3 palladium diacetate 

Downstream Products

• 4030-18-6 N-(acetyl)pyrrolidine 
• 6908-73-2 (E)-1-styrylpyrrolidine 
• 618-42-8 1-piperidin-1-yl-ethanone 
• 55606-20-7 (E)-N-styrylpiperidine 
• 1696-20-4 4-acetylmorpholine 
• 39166-25-1 (E)-N-(2-phenylethenyl)morpholine 
• 122-78-1 phenylacetaldehyde 
• 82489-29-0 (E)-N,N-diethyl-2-phenylethen-1-amine 
• 18756-03-1 (E)-(2-azidovinyl)benzene 
• 42599-24-6 E-styryl iodide 
• 4714-21-0 E-1-methyl-4-styryl-benzene 
• 698-88-4 (2,2-dichlorovinyl)benzene 
• 7436-90-0 2,2-dibromostyrene 
• 61080-12-4 4,4'-(2-phenylethene-1,1-diyl)bis(methylbenzene) 

Relevant articles and documents

Stereoselective synthesis of enol acetates by the reaction of alkenylboronates with (diacetoxyiodo)benzene and sodium iodide

Stereochemically pure (E)- and (Z)-alk-1-en-1-yl acetates have been easily prepared by acetoxylation of the (Z)-and (E)-alk-1-en-1-ylboronic acids or their esters, respectively, with (diacetoxyiodo)benzene and sodium iodide, in reasonable yields.

Carboxylic acid addition to terminal alkynes utilizing ammonium tagged Hoveyda-Grubbs catalyst supported on magnetically separable core/shell silica: A highly reusable and air compatible catalytic system

In this study, the performance of ammonium tagged Hoveyda-Grubbs catalyst supported on magnetically separable core/shell silica gel was tested on carboxylic acid addition reactions to terminal alkynes using a variety of carboxylic acid derivatives under air atmosphere. The catalytic system was found to be compatible with air atmosphere and can tolerate even non-degassed solvents. The reaction parameters such as temperature, substrate/catalyst ratio and the effect of carboxylic acid on the selectivity and yield of the reaction were investigated in details. The reaction of arylacetylenes with acetic acid yielded the corresponding E-isomer with conversion values up to 99% with a catalytic loading of 1% Ru. The reusability of the catalyst was tested using acetic acid/benzoic acid and phenylacetylene in toluene at 85 °C under air atmosphere. The catalyst was found to be highly reusable and maintained its activity up to 11th run, reaching a conversion value of 83% with minimum ruthenium leaching.

Palladium-Catalyzed Arylation of Olefins by Triarylphosphines via C-P Bond Cleavage

C-H Arylation of olefins by triarylphosphines via C-P bond cleavage has been achieved with either Pd0 or PdII catalysts. A variety of olefins and triarylphosphines are tolerated, and we inferred that both Pd0 and PdII could function directly without pre-oxidation or pre-reduction.