158720-21-9

Basic information

• Product Name: 2-<2-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone
• CAS NO: 158720-21-9
• Molecular Weight: 280.439
• Mol File: 158720-21-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-<2-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<2-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone(158720-21-9)
• EPA Substance Registry System: 2-<2-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone(158720-21-9)

Safety Data

• Hazardous Substances Data: 158720-21-9(Hazardous Substances Data)

Upstream product

• 85807-85-8 Allyloxy-tert-butyl-dimethyl-silane 
• 106-51-4 p-benzoquinone 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

Electroorganic Synthesis, 58. Synthesis of Substituted Benzoquinones and their Use for Mediated Electrochemical Conversions

Hydroxy- (1a-3a) and hydroxyalkyl-substituted benzoquinones (6a-8a, 27a), suited to be immobilized by esterification with polyacrylic acid, are prepared.Their cathodic reduction potential Ep,c (1) correlates linearly with their substituent constant.The cathodic reduction of dioxygen and the palladium(II)-catalyzed anodic oxidation of alkenes are mediated by the benzoquinones 7b, 8b and 27b, respectively. - Key Words: Benzoquinones, substituted / Cyclic voltammetry / Cathodic dioxygen reduction, mediated / Anodic Wacker oxidation, mediated