85807-85-8

Basic information

• Product Name: ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER
• Synonyms: ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER;(allyloxy)(tert-butyl)dimethylsilane(WXC08798)
• CAS NO: 85807-85-8
• Molecular Formula: C₉H₂₀OSi
• Molecular Weight: 172.34
• Mol File: 85807-85-8.mol
• Article Data: 30

Chemical Properties

• Boiling Point: 120°C / 50
• Flash Point: 32°C (90°F)
• Appearance: /
• Density: 0.811
• Refractive Index: 1.4210
• CAS DataBase Reference: ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER(85807-85-8)
• EPA Substance Registry System: ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER(85807-85-8)

Safety Data

• Hazardous Substances Data: 85807-85-8(Hazardous Substances Data)

Usage

General Description

ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER is a chemical compound with the molecular formula C10H22OSi, which is commonly used in the field of organic synthesis and materials science. It is a clear, colorless liquid with a faint sweet odor, and is soluble in organic solvents such as ether, chloroform, and benzene. ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER is known for its reactivity and ability to form useful intermediates for the synthesis of various organic compounds. It is often used as a reagent in the preparation of silicon-containing polymers, resins, and surface coatings. Additionally, it can serve as a protective group for alcohols and phenol compounds in organic synthesis, as well as a crosslinking agent in the production of silicone rubbers and sealants. Overall, ALLYL(TERT-BUTYLDIMETHY1)SILYLETHER is a versatile and important chemical in the industry due to its various applications and reactivity.

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 107-18-6 allyl alcohol 
• 114413-26-2 tert-butyldimethylsilyl glycidyl ether 

Downstream Products

• 254761-43-8 (E)-1-(tert-butyldimethylsilyloxy)-3-(4-methoxyphenyl)-2-propene 
• 223143-01-9 (4-benzyloxymethyl-penta-2,4-dienyloxy)-tert-butyl-dimethyl-silane 
• 158720-21-9 2-<2-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone 
• 158720-20-8 2-<3-(tert-butyldimethylsilyloxy)propyl>-1,4-benzoquinone 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 80594-32-7 1-<(tert-butyl)dimethylsilyl>-2-propen-1-ol 

Relevant articles and documents

Termination of living anionic polymerizations using chlorosilane derivatives. A general synthetic methodology for the synthesis of end-functionalized polymers

The transformation of living polymer chain ends is the most widely used technique to synthesize end-functionalized polymeric materials. Herein we report the development of a new synthetic methodology which is able to give very high degrees of functionalization to living anionic polymer chains. This methodology is based on termination reactions with chlorosilane derivatives containing protected functional groups and is described with particular emphasis on the introduction of primary aliphatic amines and primary emphasis on the introduction of primary aliphatic amines and primary aliphatic alcohols. The extent of functionalization was verified by using conventional techniques such as gel permeation chromatography (GPC), end group titration, multinuclear magnetic resonance spectroscopy, and TLC, but was also examined by using time-of-flight secondary ion mass spectrometry (TOF-SIMS). The usefulness of these materials for construction of supramolecular assemblies is illustrated by the coupling of the polymeric amine to [Ru(bpy)2(4-CH34′-CO2Hbpy)]-(PF6)2 (bpy - 2,2′-bipyridine).

Branch-Selective Hydroarylation: Iodoarene-Olefin Cross-Coupling

A combination of cobalt and nickel catalytic cycles enables a highly branch-selective (Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are consistent with hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a nickel cycle.

Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand

A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1). (Chemical Equation Presented).