158817-21-1Relevant articles and documents
Photoredox/Nickel-Catalyzed Single-Electron Tsuji–Trost Reaction: Development and Mechanistic Insights
Matsui, Jennifer K.,Gutiérrez-Bonet, álvaro,Rotella, Madeline,Alam, Rauful,Gutierrez, Osvaldo,Molander, Gary A.
supporting information, p. 15847 - 15851 (2018/11/23)
A regioselective, nickel-catalyzed photoredox allylation of secondary, benzyl, and α-alkoxy radical precursors is disclosed. Through this manifold, a variety of linear allylic alcohols and allylated monosaccharides are accessible in high yields under mild reaction conditions. Quantum mechanical calculations [DFT and DLPNO-CCSD(T)] support the mechanistic hypothesis of a Ni0 to NiII oxidative addition pathway followed by radical addition and inner-sphere allylation.
Synthesis of the C1-C9 fragment of the potent antitumor agent dictyostatin
Dias, Luiz C.,Sant'ana, Danilo P.,Vieira, Ygor W.,Gonc?alves, Caroline C.S.,Lima, Dimas J.P.
, p. 344 - 348 (2012/06/01)
We describe herein a short and efficient synthesis of the C1-C9 fragment of the potent antitumor agent dictyostatin. Notable features of this approach include a Sharpless asymmetric epoxidation followed by epoxide opening under Myashita's conditions to in
Stereoconvergent synthesis of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A
Yadav,Raj Kumar,Sabitha
, p. 463 - 466 (2008/09/18)
Stereoconvergent syntheses of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A are reported.