1590442-52-6

Basic information

• Product Name: C₂₇H₁₈F₈NOP
• CAS NO: 1590442-52-6
• Molecular Weight: 555.407
• Mol File: 1590442-52-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₁₈F₈NOP(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₁₈F₈NOP(1590442-52-6)
• EPA Substance Registry System: C₂₇H₁₈F₈NOP(1590442-52-6)

Safety Data

• Hazardous Substances Data: 1590442-52-6(Hazardous Substances Data)

Upstream product

• 771-60-8 2,3,4,5,6-pentafluoroaniline 
• 4129-40-2 di(p-tolyl)phosphinic chloride 
• 1590442-13-9 C₂₀H₁₅F₅NOP 
• 128796-39-4 4-trifluoromethylphenylboronic acid 

Relevant articles and documents

PdII-catalyzed mild C-H ortho arylation and intramolecular amination oriented by a phosphinamide group

A novel protocol for the Pd-catalyzed ortho-arylation of aryl phosphinamide with boronic acid is reported. By using phosphinamide as a new directing group, the reaction proceeds efficiently under mild conditions at 40 °C. Mechanistic studies reveal that the reaction proceeds via a PdII to Pd0 cycle. The phosphinamide group is also shown to be an effective orienting group for direct C-H amination.