1601485-39-5Relevant articles and documents
C2H2 adsorption in three isostructural metal-organic frameworks: Boosting C2H2 uptake by rational arrangement of nitrogen sites
Song, Chengling,Jiao, Jingjing,Lin, Qiyi,Liu, Huimin,He, Yabing
, p. 4563 - 4569 (2016)
Replacing the benzene spacer in the organic linker 5,5′-(benzene-1,4-diyl)diisophthalate with the nitrogen containing heterocyclic rings, namely, pyrazine, pyridazine, and pyrimidine results in three organic linkers, which were reacted with copper ions un
A porous metal-organic framework with dynamic pyrimidine groups exhibiting record high methane storage working capacity
Li, Bin,Wen, Hui-Min,Wang, Hailong,Wu, Hui,Tyagi, Madhusudan,Yildirim, Taner,Zhou, Wei,Chen, Banglin
supporting information, p. 6207 - 6210 (2014/05/20)
We have realized a new porous metal-organic framework UTSA-76a with pyrimidine groups on the linker, exhibiting high volumetric methane uptake of ～260 cm3 (STP) cm-3 at 298 K and 65 bar, and record high working capacity of ～200 cm3 (STP) cm-3 (between 5 and 65 bar). Such exceptionally high working capacity is attributed to the central dynamic pyrimidine groups within UTSA-76a, which are capable of adjusting their orientations to optimize the methane packing at high pressure, as revealed by computational studies and neutron scattering experiments.
