160560-48-5Relevant articles and documents
Asymmetric synthesis of tetrahydrofurans by diastereoselective [3+2] cycloaddition of allylsilanes with α-keto esters bearing an optically active cyclitol as a chiral auxiliary
Akiyama, Takahiko,Yasusa, Takuya,Ishikawa, Keiichiro,Ozaki, Shoichiro
, p. 8401 - 8404 (1994)
Tin (IV) chloride mediated [3+2] cycloadditions of allylsilanes with optically active α-keto esters derived from L-quebrachitol afforded tetrahydrofuran derivatives via 1,2-silyl migration with high level of diastereoselectivity. Removal of the chiral aux