161267-45-4

Basic information

• Product Name: 2,2'-bis(2-methoxyacetamido)diphenyl ether
• Synonyms: 2,2'-bis(2-methoxyacetamido)diphenyl ether
• CAS NO: 161267-45-4
• Molecular Weight: 344.367
• Mol File: 161267-45-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2'-bis(2-methoxyacetamido)diphenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-bis(2-methoxyacetamido)diphenyl ether(161267-45-4)
• EPA Substance Registry System: 2,2'-bis(2-methoxyacetamido)diphenyl ether(161267-45-4)

Safety Data

• Hazardous Substances Data: 161267-45-4(Hazardous Substances Data)

Upstream product

• 2217-65-4 bis(2-nitrophenyl)ether 
• 38870-89-2 Methoxyacetyl chloride 
• 24878-25-9 bis(2-aminophenyl)ether 

Downstream Products

• 151621-84-0 bis<2-(2-methoxyethylamino)phenyl>ether 

Relevant articles and documents

Self-Assembly in the Metallation of Bis(aminoaryl) Ethers

The dilithiation of 2,2'-bis(2-methoxyethylamino)diphenyl ether (4) and 2,2'-bis(N,N-dimethylethylenediamino)diphenyl ether (7) in the absence of any Lewis base donor resulted in the formation of dimeric complexes 8 and 9, respectively, containing the unprecedented Li4O2N4 "adamantanoid" metal core as a consequence of the self-recognition and self-assembly involving the two metallated subunits.In contrast, on monometallation using particular conditions, e.g. sodium hydride in the presence of Lewis base donor, the same ligands undergo a Smiles-type rearrangement, providing the first example of such a reaction involving an amine and a deactivated aromatic system.The conditions needed to promote this rearrangement have been invstigated.