167637-13-0

Basic information

• Product Name: [Au(C=CHCH=NS)(PPh₃)]
• CAS NO: 167637-13-0
• Molecular Weight: 543.379
• Mol File: 167637-13-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Au(C=CHCH=NS)(PPh₃)](CAS DataBase Reference)
• NIST Chemistry Reference: [Au(C=CHCH=NS)(PPh₃)](167637-13-0)
• EPA Substance Registry System: [Au(C=CHCH=NS)(PPh₃)](167637-13-0)

Safety Data

• Hazardous Substances Data: 167637-13-0(Hazardous Substances Data)

Upstream product

• 288-16-4 isothiazol 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 

Relevant articles and documents

Preparation and Characterization of the First Isothiazolyl and Isothiazolinylidene Complexes of Gold(I)

Isothiazolyl complexes have been synthesized by the addition of isothiazol-5-yllithium to gold(I) chloride or tetrahydrothiophene(pentafluorophenyl)gold complexes.Protonation or alkylation of these isothiazolyl complexes yielded the corresponding isothiazolinylidene complexes.The mono(isothiazolyl)-aurate and mono(isothiazolinylidene) complexes undergo homoleptic rearrangement.The molecular structure of the mono(isothiazolyl) complex shows a gold-carbon bond length of 2.032(7) Angstroem.