288-16-4Relevant articles and documents
PHOTOLYSIS OF BROMOTHIAZOLES IN HYDROGEN-DONATING SOLVENTS. A THEORETICAL STUDY AND PHYSICAL PROPERTIES OF BROMOTHIAZOLES
Parkanyi, Cyril,Vernin, Gaston,Zamkostian, Rose-Marie,Metzger, Jacques
, p. 1077 - 1089 (2007/10/02)
Uv irradiation of bromothiazoles in various organic solvents (methanol, ether, cyclohexane) produces thiazole and the isomeric isothiazole as the main reaction products.The reactivity of monobromothiazoles in this reaction decreases in the order: 2-bromothiazole > 5-bromothiazole >> 4-bromothiazole.The PPP (LCI-SCF-MO) calculations of bromothiazoles were used to interpret and discuss their various properties.The uv, NMR, and mass spectra of bromothiazoles were measured.