1688-17-1

Basic information

• Product Name: Benzene, (1-chloro-2,2-dimethylpropyl)-
• CAS NO: 1688-17-1
• Molecular Formula: C11H15Cl
• Molecular Weight: 182.693
• Mol File: 1688-17-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, (1-chloro-2,2-dimethylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-chloro-2,2-dimethylpropyl)-(1688-17-1)
• EPA Substance Registry System: Benzene, (1-chloro-2,2-dimethylpropyl)-(1688-17-1)

Safety Data

• Hazardous Substances Data: 1688-17-1(Hazardous Substances Data)

Upstream product

• 938-16-9 2,2-dimethylpropiophenone 
• 23439-91-0 (R)-(+)-α-phenylneopentyl alcohol 
• 100-58-3 phenylmagnesium bromide 
• 630-19-3 pivalaldehyde 
• 75-28-5 Isobutane 
• 4460-46-2 3-chloro-3-phenyl-3H-diazirine 
• 1007-26-7 (2,2-dimethyl-1-propyl)benzene 
• 23587-78-2 trimethyl-(2,2-dimethyl-1-phenylpropoxy)silane 
• 3835-64-1 2,2-dimethyl-1-phenylpropan-1-ol 

Downstream Products

• 70712-85-5 1-phenyl-2,2-dimethyl-1-propyl bromide 
• 42083-48-7 (+/-)-tert-butyl(2,2-dimethyl-1-phenylpropyl)sulfane 
• 62558-05-8 2,2-dimethyl-1-(4-nitrophenyl)propan-1-one 
• 13491-16-2 (R)-(-)-α-tert-butylphenylacetic acid 
• 13490-71-6 (S)-(+)-α-tert-butylphenylacetic acid 
• 68525-39-3 d,l-2,2,5,5-Tetramethyl-3,4-diphenylhexane 
• 62678-51-7 meso-2,2,5,5-Tetramethyl-3,4-diphenylhexane 
• 27561-34-8 meso-3,4-Diphenyl-2,2,5,5-tetramethyl-hexan 
• 62558-02-5 1-(1-chloro-2,2-dimethylpropyl)-4-nitrobenzene 
• 13490-70-5 (+/-)-α-tert-butylphenylacetic acid 

Relevant articles and documents

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Iron catalyzed halogenation of benzylic aldehydes and ketones

A simple and efficient iron-catalyzed method for chlorination of aromatic carbonyl compounds is reported. By using 4-10 mol% Fe(iii) oxo acetate catalyst, prepared by solid state atmospheric oxidation of Fe(ii) acetate, in combination with triethylsilane and chlorotrimethylsilane, hydrosilylation of benzylic carbonyl compounds with subsequent chlorination is achieved within a few hours at room temperature. This new method is mild and rapid compared to the conventional two step approach involving reduction and chlorination reactions in separate stages. Development of synthetic methodology is also supplemented here by kinetic investigation of the reaction mechanism, which supports the tentative mechanisms suggested previously for similar reactions. This journal is

Dramatic Reversal of Diastereoselectivity in an N-Acyliminium Ion Cyclization Leading to Hexahydropyrroloisoquinolines. A Case of Competing Steric Interactions

The N-acyliminium ion cyclization 1 -> 2 + 3 (eq 1) with various aliphatic substituents (R = ethyl, cyclohexyl, and tert-butyl) was carried out, as an extension of our work in ref 2.The following 2:3 ratios were obtained: 39:61, 12:88, and 15:85, respecti