1700-10-3 Usage
Description
1,3-Cyclooctadiene is an organic compound with a molecular formula of C8H12. It is a colorless liquid that is characterized by its bicyclic structure, featuring two carbon-carbon double bonds. 1,3-Cyclooctadiene is known for its unique chemical properties and reactivity, making it a versatile building block in various chemical reactions and applications.
Uses
1. Used in Chemical Synthesis:
1,3-Cyclooctadiene is used as a reagent for the synthesis of catalytically active membrane-like devices. Its unique structure allows it to participate in various chemical reactions, making it a valuable component in the development of advanced materials with specific catalytic properties.
2. Used in Pharmaceutical Industry:
1,3-Cyclooctadiene is used as a starting material in the preparation of 2-cyclooct-2-en-1-yl-1,3-cyclooctadiene, a novel bicyclic triene. 1,3-Cyclooctadiene has potential applications in the pharmaceutical industry, particularly in the development of new drugs and therapeutic agents.
3. Used in Supramolecular Chemistry:
1,3-Cyclooctadiene has been studied in the context of enantiodifferentiating geometrical photoisomerizations using "cyclodextrin nanosponge" as a supramolecular sensitizing host. This research contributes to the understanding of the compound's behavior in supramolecular systems and its potential applications in the field of supramolecular chemistry.
4. Used in Catalyst Development:
Dendrimer-encapsulated Pd-Rh bimetallic nanoparticle catalyzed partial hydrogenation of 1,3-cyclooctadiene has been reported. This application highlights the compound's role in the development of new catalysts, which are essential for various industrial processes and chemical reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 1700-10-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,0 and 0 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1700-10:
(6*1)+(5*7)+(4*0)+(3*0)+(2*1)+(1*0)=43
43 % 10 = 3
So 1700-10-3 is a valid CAS Registry Number.
InChI:InChI=1/C8H12/c1-2-4-6-8-7-5-3-1/h1-4H,5-8H2
1700-10-3Relevant articles and documents
Enantiodifferentiation in the Photoisomerization of (Z,Z)-1,3-Cyclooctadiene in the Cavity of γ-Cyclodextrin-Curcubit[6]uril-Wheeled [4]Rotaxanes with an Encapsulated Photosensitizer
Yan, Zhiqiang,Huang, Qinfei,Liang, Wenting,Yu, Xingke,Zhou, Dayang,Wu, Wanhua,Chruma, Jason J.,Yang, Cheng
, p. 898 - 901 (2017)
A biphenyl photosensitizer axle was implanted into the cavities of native and capped γ-cyclodextrins through rotaxanation using a cucubit[6]uril-templated azide-alkyne 1,3-dipolar cycloaddition, resulting in the construction of highly defined chiral binding/sensitizing sites. The orientation and interaction of the axle and capping moieties at the ground and excited states were interrogated by NMR, UV-vis, circular dichroism, and fluorescence spectroscopic studies. In situ photoisomerization of (Z,Z)-1,3-cyclooctadiene sensitized in the cavity of these [4]rotaxanes afforded (Z,E)-1,3-cyclooctadiene in up to 15.3% ee, which represents the highest level of enantiodifferentiation obtained to date for this supramolecular photochirogenesis.
Resolution, Circular Dichroism Spectrum, Molecular Structure, and Absolute Configuration of cis,trans-1,3-Cyclooctadiene
Isaksson, Roland,Roschester, Jan,Sandstroem, Jan,Wistrand, Lars-Goeran
, p. 4074 - 4075 (1985)
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Investigation of Rearrangement Reactions of Cyclic Allyl and Pentadienyl Anions
Sustmann, Reiner,Dern, Heinz-Juergen
, p. 2958 - 2971 (2007/10/02)
Bicyclohexenyl anion (1) and bicycloheptenyl anion (2) rearrange in THF to monocyclic pentadienyl anions, whereas bicyclooctenyl anion 3 is stable under the reaction conditions. 3 in contrary is formed by the known electrocyclic ring closure of cyclooctadienyl anion 7.Rearrangements of cyclopentenyl anion and pentadienyl anion are not detected.Cyclic allyl anions are alkylated by ethene, formed by cleavage of THF with base or independently added. 6,6-Dimethylcyclohexadienyl anion undergoes slow fragmentation to toluene at room temperature.