172489-94-0Relevant articles and documents
Synthesis and characterization of authentic standards for the analysis of ribofuranose-containing carbohydrates by the reductive-cleavage method
Rozanas, Christine R.,Wang, Nan,Vidlock, Kathy,Gray, Gary R.
, p. 99 - 110 (1995)
Described herein is the synthesis of all positional isomers of partially methylated and acetylated or benzoylated 1,4-anhydro-D-ribitol.The benzoates are generated simultaneously from 1,4-anhydro-D-ribitol by sequential partial methylation and benzoylation or sequential partial benzoylation and methylation.The individual isomers are obtained in pure form by high-performance liquid chromatography.Debenzoylation and acetylation provided the corresponding acetates.Reported herein are the 1H NMR spectra of the benzoates and the electron-ionization mass spectra of the acetates and the tri-O-methyl derivative and also for the acetates and the tri-O-methyl derivative, their linear temperature programmed gas-liquid chromatography retention indices on three different capillary columns.Keywords: Reductive-cleavage; D-Ribitol, 1,4-anhydro, partially methylated and acylated