17293-03-7Relevant articles and documents
Method for preparing 2, 4, 6-trichlorobenzonitrile by ammonia oxidation method, special catalyst and preparation method
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Paragraph 0023-0029, (2020/08/22)
The invention discloses a method for preparing 2, 4, 6-trichlorobenzonitrile by an ammonia oxidation method. According to the method, 1, 3, 5-trichlorobenzene is taken as a raw material, 2, 4, 6-trichlorobenzyl chloride is obtained under the action of a special chloromethylation catalyst, and then 2, 4, 6-trichlorobenzonitrile is obtained under the action of a special ammoxidation catalyst. The invention further discloses a special catalyst for preparing 2, 4, 6-trichlorobenzonitrile and a preparation method. The special chloromethylation catalyst disclosed by the invention can be used for better catalyzing the reaction of 1, 3, 5-trichlorobenzene chloride and formaldehyde or paraformaldehyde and a chlorine atom donor to efficiently obtain 2, 4, 6-trichlorobenzyl chloride; and the specialammoxidation catalyst can well catalyze the reaction of 2, 4, 6-trichlorobenzyl chloride to obtain 2, 4, 6-trichlorobenzonitrile. The special catalyst disclosed by the invention has the advantages ofhigh activity, high product yield, good selectivity, high product purity, long service life and simple process; the preparation method has the advantages of short reaction route, low reaction temperature, high yield and high selectivity.
PYRAZOLECARBOXAMIDE DERIVATIVES AND THEIR USE AS MICROBIOCIDES
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Paragraph 0166-0169, (2013/03/28)
Compounds of Formula (I) wherein R1 is C1-C4alkyl or C1-C4 haloalkyl; R2 is C1-C4alkyl; R3 is hydrogen or halogen; R4 is hydrogen, C1-C4alkyl or C1-C4halogenalkyl; R5 is hydrogen, halogen, C1-C4alkyl or C1-C4halogenalkyl; R6 is hydrogen, halogen, C1-C4alkyl, C2-C6alkenyl or C3-C6alkinyl; R7 is hydrogen, halogen, C1-C6alkyl, C2-C6alkenyl, C3-C6alkinyl, C3-C6cycloalkyl-C3-C6alkinyl, halophenoxy, halophenyi, C1-C6haloalkyl, C1-C6haloakoxy, C2-C6haloalkenyl, or C2-C6haloalkenyloxy; R8 is hydrogen, halogen, C1-C4alkyl, C2-C6alkenyl or C3-C6alkinyl; with the provisio that at least one of R6, R7 and R8 is different from hydrogen; n is 0 or 1, are suitable for use as microbriocides.
NOVEL PYRAZOLE-4-N-ALKOXYCARBOXAMIDES AS MICROBIOCIDES
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Page/Page column 18, (2011/10/10)
Compounds of formula (I) in which the substituents are as defined in claim 1, are suitable for use as microbiocides.