17373-17-0

Basic information

• Product Name: CIS,TRANS,TRANS-3,5-DIMETHYLCYCLOHEXANOL
• Synonyms: CIS,TRANS,TRANS-3,5-DIMETHYLCYCLOHEXANOL
• CAS NO: 17373-17-0
• Molecular Formula: C₈H₁₆O
• Molecular Weight: 128.21204
• EINECS: 226-630-8
• Mol File: 17373-17-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 187°Cat760mmHg
• Flash Point: 73.3°C
• Appearance: /
• Density: 0.893g/cm³
• Vapor Pressure: 0.18mmHg at 25°C
• Refractive Index: 1.451
• CAS DataBase Reference: CIS,TRANS,TRANS-3,5-DIMETHYLCYCLOHEXANOL(CAS DataBase Reference)
• NIST Chemistry Reference: CIS,TRANS,TRANS-3,5-DIMETHYLCYCLOHEXANOL(17373-17-0)
• EPA Substance Registry System: CIS,TRANS,TRANS-3,5-DIMETHYLCYCLOHEXANOL(17373-17-0)

Safety Data

• Hazardous Substances Data: 17373-17-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H16O/c1-6-3-7(2)5-8(9)4-6/h6-9H,3-5H2,1-2H3

Upstream product

• 2320-30-1 trans-3,5-dimethylcyclohexanone 
• 1123-09-7 3,5-dimethyl-2-cyclohexen-1-one 
• 7647-01-0 hydrogenchloride 
• 7214-52-0 3,5-dimethyl-cyclohexanone 
• 64-19-7 acetic acid 
• 108-68-9 3,5-Dimethylphenol 
• 104319-08-6 Toluene-4-sulfonic acid (1R,3S,5R)-3,5-dimethyl-cyclohexyl ester 

Downstream Products

• 70443-68-4 phthalic acid bis-(3c.5c-dimethyl-cyclohexyl-(r)-ester) 
• 109652-61-1 phthalic acid mono-(3c,5c-dimethyl-cyclohex-r-yl ester) 
• 92701-99-0 phenyl-carbamic acid (1alpha,3alpha,5alpha)-3,5-dimethyl-cyclohexyl ester 
• 92701-99-0 phenyl-carbamic acid (1alpha,3beta,5beta)-3,5-dimethyl-cyclohexyl ester 
• 767-13-5 3,5-dimethylcyclohexanol 
• 109652-61-1 phthalic acid mono-(3t,5t-dimethyl-cyclohex-r-yl ester) 
• 70443-68-4 phthalic acid bis-(3t.5t-dimethyl-cyclohexyl-(r)-ester) 
• 109067-78-9 3.5-dinitro-benzoic acid-(3t.5t-dimethyl-cyclohexyl-(r)-ester) 
• 7214-52-0 3,5-dimethyl-cyclohexanone 
• 109067-78-9 (+/-)-3.5-dinitro-benzoic acid-(3r.5t-dimethyl-cyclohexyl ester) 

Relevant articles and documents

Crystal Structural Study on 2:1 Complexes of Equatorial Isomers of 3,5-Dimethylcyclohexanone and 3,5-Dimethylcyclohexanol with 1,1,6,6-Tetraphenylhexa-2,4-diyne-1,6-diol

Selective inclusion of the diequatorial isomer of 3,5-dimethylcyclohexanone and the triequatorial isomer of 3,5-dimethylcyclohexanol by 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol was observed.The crystal structure of these complexes was studied.

Highly chemoselective catalytic hydrogenation of unsaturated ketones and aldehydes to unsaturated alcohols using phosphine-stabilized copper(I) hydride complexes

A base metal hydrogenation catalyst composed of the phenyldimethylphosphine-stabilized copper(I) hydride complex provides for the highly chemoselective hydrogenation of unsaturated ketones and aldehydes to unsaturated alcohols, including the regioselective 1,2-reduction of α,β- unsaturated ketones and aldehydes to allylic alcohols. The active catalyst can be derived in situ by phosphine exchange using commercial [(Ph3P)CuH]6 or from the reaction of copper(l) chloride, sodium tert-butoxide, and dimethylphenylphosphine under hydrogen. The catalyst derived from 1,1,1- tris(diphenylphosphinomethyl)ethane is mechanistically interesting but less synthetically useful. (C) 2000 Elsevier Science Ltd.

Hydride-Mediated Homogeneous Catalysis. Catalytic Reduction of α,β-Unsaturated Ketones Using 6 and H2

Hydride-mediated reduction of α,β-unsaturated ketones catalytic in the hydride reagent is reported using 6 and molecular hydrogen.The reaction proceeds at room temperature and is highly regioselective, affording either the product of conjugate reduction or complete 1,4- and 1,2-reduction to the saturated alcohol, depending on reaction conditions.In the presence of excess phosphine, the process is homogeneous and chemoselective: isolated double bonds are not hydrogenated, even under forcing conditions.This novel catalytic reduction appears to proceed viathe heterolytic activation of molecular hydrogen by highly reactive copper(I) enolate and alkoxide intermediates.