17482-09-6Relevant articles and documents
Convergent, stereoselective synthesis of the GHIJ fragment of brevetoxin A
Crimmins, Michael T.,Zuccarello, J. Lucas,Cleary, Pamela A.,Parrish, Jonathan D.
, p. 159 - 162 (2007/10/03)
(Chemical Equation Presented) A stereoselective synthesis of the GHIJ fragment of brevetoxin A utilizing a convergent assembly strategy is described. Glycolate alkylation, ring-closing metathesis, and Hosomi-Sakurai reactions were central operations in the construction of the G ring and J ring subunits, which were united through a Horner-Wadsworth-Emmons coupling. Subsequent dehydrative cyclization produced an endocyclic enol ether that was further elaborated to the tetracyclic GHIJ fragment of brevetoxin A.
A convergent coupling strategy for the formation of polycyclic ethers: Stereoselective synthesis of the BCDE fragment of brevetoxin A
Crimmins, Michael T.,McDougall, Patrick J.,Emmitte, Kyle A.
, p. 4033 - 4036 (2007/10/03)
(Chemical Equation Presented) A stereoselective synthesis of the BCDE fragment of brevetoxin A has been completed. anti-Glycolate aldol, glycolate alkylation, and ring-closing metathesis reactions were employed as key bond-forming events. A convergent ass
Totalsynthese von Mycinolid V, dem Aglycon eines Makrolid-Antibioticums der Mycinamycin-Reihe
Ditrich, Klaus,Bube, Tomas,Stuermer, Rainer,Hoffmann, Reinhard W.
, p. 1016 - 1018 (2007/10/02)
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