17704-04-0Relevant articles and documents
An intermolecular C-H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines
Rank, Christian K.,Jones, Alexander W.,Wall, Tatjana,Di Martino-Fumo, Patrick,Schr?ck, Sarah,Gerhards, Markus,Patureau, Frederic W.
supporting information, p. 13749 - 13752 (2019/11/19)
Highly π-extended hetero-cyclic/aromatic skeletons are of great importance as they can be utilized in many organic material based technologies. Therefore, developing efficient, pre-activation-free, synthetic procedures for the rapid build-up of these complex structures remains a high priority objective. The herein presented approach delivers highly fused carbazole skeletons from simple naphthylamine derivatives.
Nitroxide Radicals. Part 21. Spontaneous Decomposition of N-Aryl 1- and 2-Naphthyl Nitroxides
Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon
, p. 1759 - 1764 (2007/10/02)
N-Aryl 1-naphthyl nitroxides self-react in solution to give the corresponding secondary amines and N-aryl-1,4-naphthoquinone imines.When reaction at the 4-naphthyl position is hindered by substituents benzoquinone imines are also produced.N-Phenyl 2-naphthyl nitroxide under similar conditions gives the corresponding amine and 2-phenylamino-1,4-naphthoquinone via a 1,2-naphthoquinone imine N-oxide intermediate.
