178616-60-9

Basic information

• Product Name: (2R*S*,1'R*)-Methyl 2-<2-(6-methylene-2,2-dimethylcyclohexyl)ethyl>-3-oxobutanoate
• CAS NO: 178616-60-9
• Molecular Weight: 266.381
• Mol File: 178616-60-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R*S*,1'R*)-Methyl 2-<2-(6-methylene-2,2-dimethylcyclohexyl)ethyl>-3-oxobutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R*S*,1'R*)-Methyl 2-<2-(6-methylene-2,2-dimethylcyclohexyl)ethyl>-3-oxobutanoate(178616-60-9)
• EPA Substance Registry System: (2R*S*,1'R*)-Methyl 2-<2-(6-methylene-2,2-dimethylcyclohexyl)ethyl>-3-oxobutanoate(178616-60-9)

Safety Data

• Hazardous Substances Data: 178616-60-9(Hazardous Substances Data)

Upstream product

• 178616-56-3 6-[1-Butylsulfanyl-meth-(Z)-ylidene]-2,2-dimethyl-cyclohexanol 
• 88214-43-1 1-<2'-(p-Toluenesulfonyl)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 76337-18-3 3,3-Dimethylcyclohex-1-ene-1-carbaldehyde 
• 67218-06-8 6-(butylsulfanyl-methylene)-2,2-dimethyl-cyclohexanone 
• 84078-59-1 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol 
• 105-45-3 acetoacetic acid methyl ester 
• 178616-59-6 (+/-)-2-(2-Iodoethyl)-3-methylene-1,1-dimethylcyclohexane 
• 99440-31-0 Ethyl 2-(6,6-dimethyl-2-methylenecyclohexyl)ethanoate 

Downstream Products

• 178616-52-9 Toluene-4-sulfonic acid 2-[2-(2-hydroxy-2,6,6-trimethyl-cyclohexyl)-ethyl]-3-oxo-butyl ester 
• 178616-51-8 3-Hydroxymethyl-5-(2-hydroxy-2,6,6-trimethyl-cyclohexyl)-pentan-2-one 
• 145631-62-5 5-((1R,2S)-2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-3-methylene-pentan-2-one 
• 145631-62-5 5-((1R,2R)-2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-3-methylene-pentan-2-one 
• 178616-50-7 2-[2-(2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-ethyl]-butane-1,3-diol 

Relevant articles and documents

Synthesis of mono- and sesquiterpenoids, XXV: Synthesis of (6R*,7R*)-7-hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the racemate of the antibacterial sesquiterpene from premna oligotricha, and its (6R*,7R*) isomer

The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)-1 and (±)-2. VCH Verlagsgesellschaft mbH, 1996.