84078-59-1

Basic information

• Product Name: 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol
• Synonyms: 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol
• CAS NO: 84078-59-1
• Molecular Weight: 168.279
• Mol File: 84078-59-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol(84078-59-1)
• EPA Substance Registry System: 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol(84078-59-1)

Safety Data

• Hazardous Substances Data: 84078-59-1(Hazardous Substances Data)

Upstream product

• 547-15-9 2-(6',6'-Dimethyl-2'-methylenecyclohexyl)ethanal 
• 132912-39-1 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 105-45-3 acetoacetic acid methyl ester 
• 178616-59-6 (+/-)-2-(2-Iodoethyl)-3-methylene-1,1-dimethylcyclohexane 
• 99440-31-0 Ethyl 2-(6,6-dimethyl-2-methylenecyclohexyl)ethanoate 
• 72892-61-6 γ-Homocyclogeranyl acetate 
• 472-65-1 2,4,4-trimethyl-3-(2'-hydroxymethyl)-2-cyclohexene 
• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 132912-38-0 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-oxo-6,6-dimethylcyclohexane 
• 132912-37-9 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-hydroxy-6,6-dimethylcyclohexane 
• 132912-34-6 Methyl 2-Allyl-3,3-dimethyl-1-oxocyclohexane-2-carboxylate 
• 132912-36-8 2-(3',3'-Dimethyl-1'-hydroxycyclohexyl)ethanol 
• 57074-03-0 2-allyl-3,3-dimethylcyclohexan-1-one 
• 71135-95-0 methyl 2,2-dimethyl-6-oxocyclohexanecarboxylate 

Downstream Products

• 547-15-9 2-(6',6'-Dimethyl-2'-methylenecyclohexyl)ethanal 
• 178616-59-6 (+/-)-2-(2-Iodoethyl)-3-methylene-1,1-dimethylcyclohexane 
• 163041-14-3 Methyl 2,3-dihydro-2-methyl-2-[2-(2,2-dimethyl-6-methylenecyclohexyl)ethyl]-4-oxo-4H-1-benzopyran-3-carboxylate 
• 178616-60-9 (2R*S*,1'R*)-Methyl 2-<2-(6-methylene-2,2-dimethylcyclohexyl)ethyl>-3-oxobutanoate 
• 178616-50-7 2-[2-(2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-ethyl]-butane-1,3-diol 
• 145631-62-5 5-((1R,2R)-2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-3-methylene-pentan-2-one 
• 145631-62-5 5-((1R,2S)-2-Hydroxy-2,6,6-trimethyl-cyclohexyl)-3-methylene-pentan-2-one 
• 178616-51-8 3-Hydroxymethyl-5-(2-hydroxy-2,6,6-trimethyl-cyclohexyl)-pentan-2-one 
• 178616-52-9 Toluene-4-sulfonic acid 2-[2-(2-hydroxy-2,6,6-trimethyl-cyclohexyl)-ethyl]-3-oxo-butyl ester 
• 17283-81-7 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on 
• 132912-40-4 1-(2'-Cyanoethyl)-2-methylene-6,6-dimethylcyclohexane 
• 13720-12-2 4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one 
• 95452-03-2 3-(2',2'-dimethyl-6'-methylidenecyclohexyl)propionic acid 
• 132912-42-6 3-(2,2-Dimethyl-6-methylene-cyclohexyl)-1-methyl-propylideneamine 

Relevant articles and documents

A formal total synthesis of salvadione

The tricyclic 6-7-6 core structure of the triterpene salvadione (1) was obtained in an efficient manner from the aryl bromide 16 and the alkyl iodide 35 carrying a methylenecyclohexane group at the terminus. Alkylation of the anion derived from 16 with th

Synthesis of mono- and sesquiterpenoids, XXV: Synthesis of (6R*,7R*)-7-hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the racemate of the antibacterial sesquiterpene from premna oligotricha, and its (6R*,7R*) isomer

The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)-1 and (±)-2. VCH Verlagsgesellschaft mbH, 1996.

Total Synthesis of Dehydroambliol-A and Its Unnatural Z Isomer

Convergent total syntheses of dehydroambliol-A (1a), its unnatural Z isomer 1b, and ambliofuran (2) are described.The syntheses utilized 2-(3'-furyl)-1,3-dithiane (6) as a common intermediate.Analysis of their proton and carbon magnetic resonance spectra confirm that in the natural product dehydroambliol-A and in synthetic dehydroambliol-A the Δ7-bond possesses the E geometry, while in the unnatural isomer of dehydroambliol-A, the Δ7-bond is of the Z configuration.