17876-59-4

Basic information

• Product Name: chloro(diethyl)phenylsilane
• CAS NO: 17876-59-4
• Molecular Formula: C₁₀H₁₅ClSi
• Molecular Weight: 198.7646
• Mol File: 17876-59-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 236.8°C at 760 mmHg
• Flash Point: 88.9°C
• Density: 0.97g/cm³
• Vapor Pressure: 0.0712mmHg at 25°C
• Refractive Index: 1.491
• CAS DataBase Reference: chloro(diethyl)phenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(diethyl)phenylsilane(17876-59-4)
• EPA Substance Registry System: chloro(diethyl)phenylsilane(17876-59-4)

Safety Data

• Hazardous Substances Data: 17876-59-4(Hazardous Substances Data)

Upstream product

• 591-51-5 phenyllithium 
• 1719-53-5 diethyldichlorosilane 
• 994-30-9 triethylsilyl chloride 
• 80-10-4 diphenylsilyl dichloride 
• 1125-27-5 dichloro(ethyl)phenylsilane 
• 97-93-8 triethylaluminum 
• 98-13-5 Phenyltrichlorosilane 

Downstream Products

• 18032-41-2 diethyl-(2-chloro-ethoxy)-phenyl-silane 
• 18401-79-1 1,1-diethyl-3,3,3-trimethyl-1-phenyl-disiloxane 
• 18858-62-3 1,1-diethyl-1,3,3,3-tetraphenyl-disiloxane 
• 17903-63-8 diethyl(phenyl)silanol 
• 17898-81-6 Pentaethyl-phenyl-disilan 
• 18586-57-7 1,1,2,2-Tetraethyl-1,2-diphenyl-disilan 
• 14579-22-7 Diaethyl-aethinyl-phenyl-silan 
• 18586-51-1 1,1,3,3-tetraethyl-1,3-diphenyl-disiloxane 
• 1116155-80-6 2-bromophenyl diethylphenylsilyl ether 
• 1394167-01-1 diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane 
• 20156-44-9 1,1-Diethyl-1,2,2,2-tetraphenyl-disilan 
• 14579-23-8 4-Chlor-1--3-methyl-butin-(1)-ol-(3) 
• 1896-62-4 (E)-benzalacetone 
• 950585-11-2 (1R,2S)-3-(diethylphenylsilyl)-2-phenylcyclohexane 

Relevant articles and documents

Nickel-Catalyzed Selective Cross-Coupling of Chlorosilanes with Organoaluminum Reagents

Nickel-catalyzed cross-coupling reactions of chlorosilanes with organoaluminum reagents were developed. An electron-rich Ni(0)/PCy3 complex was found to be an effective catalyst for the desired transformation. The reaction of dichlorosilanes 1 proceeded to give the corresponding monosubstituted products 2. Trichlorosilanes 4 underwent selective double substitution to furnish the corresponding monochlorosilanes 2. Overall, the selective synthesis of a series of alkylmonochlorosilanes 2 from di- and trichlorosilanes was achieved using the present catalytic systems.

Modular approach to silicon-bridged biaryls: Palladium-catalyzed intramolecular coupling of 2-(arylsilyl)aryl triflates

(Chemical Equation Presented) Bridge of Si: Intramolecular direct arylation of 2-(arylsilyl)aryl triflates is catalyzed smoothly by Pd(OAc) 2/PCy3 in the presence of Et2NH in dimethylacetamide (DMA), giving rise to the corresponding silicon-bridged biaryls in good to excellent yields. The new approach has led to the synthesis of a silicon-bridged 2-phenylindole (see scheme) that exhibits blue photoluminescence in the solid state with extremely high quantum yields.