17961-92-1Relevant articles and documents
Ruthenium-Catalyzed Isomerization of ortho-Silylanilines to Their para Isomers
Ishiga, Wataru,Ohta, Masaya,Kodama, Takuya,Tobisu, Mamoru
, p. 6714 - 6718 (2021)
The catalytic ortho to para transposition of a silyl group in aniline derivatives is described. [RuCl2(p-cymene)]2/BINAP in conjunction with a Cu(OAc)2 additive serves as a potent catalytic system. This method is also applicable to the isomerization of 2-silylpyrrole derivatives to the corresponding 3-silyl isomers.
Multinuclear NMR spectroscopic studies of aryltrimethylsilanes and aryldimethylphosphaneboranes
Albanese, Joseph A.,Gingrich, Diane E.,Schaeffer, Charles D. Jr.,Coley, Suzanne M.,Otter, Julie C.,et al.
, p. 23 - 36 (2007/10/02)
Proton, boron-11, carbon-13, silicon-29, and phosphorus-31 NMR chemical shifts and coupling constants are reported for nine ortho- and 2,6-disubstituted aryltrimethylsilanes and five similarly substituted aryldimethylphosphaneboranes.Resonances in the natural-abundance carbon-13 NMR spectra for both sets of derivatives are assigned on the basis of additivity relationships, proton-coupled spectra, and relative magnitudes of 31P-13C)> coupling constants.Carbon-13 chemical shifts and 1J(13C-1H)> coupling constants indicate that the P(BH3)(CH3)2 group is electron-withdrawing.The 13C chemical shifts of aryl C(5) carbons can be attributed to steric inhibition of resonance of about the same magnitude as that produced by ortho-Si(CH3)3.Chemical shift and coupling constant data from previous work are expanded in terms of Taft's dual substituent constants ?1 and ?R0.Least squares solutions of these equations for aryldimethylphosphaneborane derivatives provide values of 0.41 for ?1 and 0.04 for ?R0 for the P(BH3)(CH3)2 group.These constants produce reasonable agreement wit observed 13C chemical shifts and coupling constants in the ortho derivatives.
