179804-03-6Relevant articles and documents
Selectivity in 1,3-Dipolar cycloadditions of β-substituted captodative olefins - An experimental and DFT transition state study
Herrera, Rafael,Mendoza, Jorge A.,Morales, Miguel A.,Mendez, Francisco,Jimenez-Vazquez, Hugo A.,Delgado, Francisco,Tamariz, Joaquin
, p. 2352 - 2364 (2008/02/08)
Captodative olefins 1-acetylvinyl carboxylates substituted with alkyl groups at the β position, 12, strongly modified the regioselectivity of 1,3-dipolar cycloadditions with respect to the behavior observed for their unsubstituted analogs, 1. When the rea