18173-84-7

Basic information

• Product Name: Silanol, bis(1-methylethyl)-
• CAS NO: 18173-84-7
• Molecular Formula: C6H16OSi
• Molecular Weight: 132.278
• Mol File: 18173-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silanol, bis(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanol, bis(1-methylethyl)-(18173-84-7)
• EPA Substance Registry System: Silanol, bis(1-methylethyl)-(18173-84-7)

Safety Data

• Hazardous Substances Data: 18173-84-7(Hazardous Substances Data)

Upstream product

• 1068-55-9 isopropylmagnesium chloride 
• 18043-71-5 1,1,3,3-tetraisopropyldisiloxane 

Downstream Products

• 69304-44-5 3',5'-O-1,1,3,3-tetraisopropyldisiloxan-1,3-diyl-guanosine 
• 69304-37-6 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 
• 76700-77-1 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine 
• 76700-79-3 Thiocarbonic acid O-phenyl ester O-((2R,3R,3aR,9aR)-5,5,7,7-tetraisopropyl-2-methoxy-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl) ester 
• 76700-78-2 3',5'-O-(tetraisopropyl-disiloxane-1,3-diyl)-2'-O-phenoxythiocarbonyl-uridine 
• 85335-77-9 Thiocarbonic acid O-[(2R,3R,3aR,9aR)-2-(4-amino-pyrrolo[2,3-d]pyrimidin-7-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl] ester O-phenyl ester 
• 85335-74-6 Thiocarbonic acid O-[(2R,3R,3aR,9aR)-2-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl] ester O-phenyl ester 
• 85335-80-4 Thiocarbonic acid O-[(2R,3R,3aR,9aR)-2-(4-amino-5-cyano-pyrrolo[2,3-d]pyrimidin-7-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl] ester O-phenyl ester 
• 85335-72-4 Thiocarbonic acid O-[(2R,3R,3aR,9aR)-2-(2-amino-6-oxo-1,6-dihydro-purin-9-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl] ester O-phenyl ester 
• 33541-67-2 carbonylhydridotris(triphenylphosphine)iridium(I) 
• 1333-74-0 hydrogen 
• 613673-01-1 [(triphenylphosphine)2(H)2Ir(CO)(Si(i-Pr)2OH)] 
• 18043-71-5 1,1,3,3-tetraisopropyldisiloxane 

Relevant articles and documents

Oxidation of Triorganosilanes and Related Compounds by Chlorine Dioxide

Abstract: Oxidation of triethylsilane, tert-butyldimethylsilane, dimethylphenylsilane, triphenylsilane, 1,1,1,2tetramethyl-2-phenyldisilane, tris(trimethylsilyl)silane, hexamethyldisilane, tetrakis(trimethylsilyl)silane, 1,1,3,3tetraisopropyldisiloxane with chlorine dioxide was carried out. The reaction products of studied triorganosilanes with chlorine dioxide in an acetonitrile solution were the corresponding silanols and siloxanes. A mechanism explaining the formation of products and the observed regularities of the oxidation of silanes with chlorine dioxide has been proposed. A thermochemical analysis of some possible pathways in the gas phase using methods G4, G3, M05, and in an acetonitrile solution by the SMD-M05 method was carried out. The oxidation process can occur both with the participation of ionic and radical intermediates, depending on the structure of the oxidized substrate and medium.