76700-78-2Relevant articles and documents
Selective site deuteration on the sugar ring as an efficient marker of conformation in nucleosides: the C-D stretching mode of the (2'-R)--2'-deoxyuridine and its 3',5'-O-(1,1,3,3-tetraisopropyldisiloxan-1,3-diyl)-derivative
Grajcar, L.,Baron, M. H.,Becouarn, S.,Czernecki, S.,Valery, J. M.,Reiss, C.
, p. 1015 - 1022 (1994)
A uridine specifically deuterated on the deoxyribose ring at the C2', and the same compound in a more rigid form, due to a chemically fused ring (between C3' and C5'), have been synthesized.By NMR, the coupling constants J1'-2' and J3'-4'
Synthesis of 2'-Allyl-2'-Deoxynucleosides by Radical Reactions
Groetli, Morten,Undheim, Kjell
, p. 217 - 224 (2007/10/02)
2'-α-Allyl-2'-deoxynucleosides derived from uridine, cytidine, adenosine and guanosine have been synthesized in high overall yields by photolysis of appropriately protected 2'-O-phenoxythiocarbonyl derivatives in the presence of allyltributylstannane.The 2'-allyl-2'-deoxynucleosides were 5'-O-DMT-protected and converted into 2'-deoxynucleoside 3'-O-phosphoramidites to serve as monomers for oligonucleotides.
Smooth and Efficient Deoxygenation of Secondary Alcohols. A General Procedure for the Conversion of Ribonucleosides to 2'-Deoxynucleosides
Robins, Morris J.,Wilson, John S.
, p. 932 - 933 (2007/10/02)
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