182680-62-2Relevant articles and documents
A very mild and chemoselective oxidation of alcohols to carbonyl compounds
De Luca, Lidia,Giacomelli, Giampaolo,Porcheddu, Andrea
, p. 3041 - 3043 (2007/10/03)
matrixpresented Efficient oxidation of primary alcohols and β-amino alcohols to the corresponding aldehydes and α-amino aldehydes can be carried out at room temperature and in methylene chloride, using trichloroisocyanuric acid in the presence of catalytic TEMPO: aliphatic, benzylic, and allylic alcohols, and β-amino alcohols are rapidly oxidized without no overoxidation to carboxylic acids. Secondary carbinols are slowly oxidized so that the reaction is highly chemoselective.